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HfO2/SiO2 dichroic mirrors, having high reflectance at 1064 nm and high transmittance at 532 nm, play an important role in high-power laser systems. However, the half-wave hole effect, caused mainly by the refractive index inhomogeneity of hafnia, affects the spectra and application of these mirrors. Two approaches to eliminate the half-wave hole effect have been proposed. Both approaches attempt to shift the location of the half-wave hole in comparison with the original wavelength. One approach broadens the reflectance band of the first harmonic wavelength and simultaneously adjusts the central reflectance band to a longer wavelength, whereas the other approach combines the two stacks to adjust the location of the half-wave hole far away from the wavelength of interest. Two kinds of dichroic mirrors have been successfully fabricated; moreover, it was found that the method of a two-stack combination, 0.9(HL)8 and 1.1(HL)8, provides designs that can be fabricated more easily and with better quality spectral characteristics.
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http://dx.doi.org/10.1364/AO.53.000A56 | DOI Listing |
ACS Appl Mater Interfaces
February 2025
Henan Provincial Key Laboratory of Nanocomposites and Applications, Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006, China.
Due to the high configuration entropy, unique atomic arrangement, and electronic structures, high-entropy materials are being actively pursued as bifunctional catalysts for both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in rechargeable zinc-air batteries (ZABs). However, a relevant strategy to enhance the catalytic activity of high-entropy materials is still lacking. Herein, a hole doping strategy has been employed to enable the high-entropy perovskite La(CrMnFeCoNi)O to effectively catalyze the ORR and OER.
View Article and Find Full Text PDFSmall
February 2025
Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Kunming, Yunnan, 650504, China.
The design and fabrication of nanocatalysts with high accessibility and sintering resistance remain significant challenges in heterogeneous electrocatalysis. Herein, a novel catalyst is introduced that combines electronic pumping with alloy crystal facet engineering. At the nanoscale, the electronic pump leverages the chemical potential difference to drive electron migration from one region to another, separating and transferring electron-hole pairs.
View Article and Find Full Text PDFChemistry
September 2024
Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo, 162-8601, Japan.
The development of electron transport and n-type materials is still largely dominated by a limited number of organic semiconductors, with fullerenes at the forefront. In contrast, substantial progress has been made in developing hole transport and p-type materials. Therefore, expanding the range of electron acceptors, making them solution-processable, and elucidating their structural arrangement by X-ray crystallography is essential.
View Article and Find Full Text PDFThis work has implemented a diverse modification of the Sagnac interferometer to accommodate various measurement requirements, including phase shifting, pattern recognition, and a morphological analysis. These modifications were introduced to validate the adaptability and versatility of the system. To enable phase shifting using the multiple light reflection technique, a half-wave plate (HWP) was utilized with rotations at 0, /8, /4, and 3/8 radians, generating four interference patterns.
View Article and Find Full Text PDFChemosphere
August 2023
Department of Environmental Science and Engineering, Wuhan University, Wuhan, 430079, China. Electronic address:
In the last few years, coupling heterogeneous photocatalysis with persulfate (PDS) activation process is an efficient approach to generate abundant reactive oxidative species towards organic contaminant removal in water, however, the key role of PDS in photocatalytic process remains ambiguous. Herein, a novel g-CN-CeO (CN-CeO) step-scheme (S-scheme) composite was constructed to photo-degrade bisphenol A (BPA) with the presence of PDS under visible irradiation. At 2.
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