Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides.

Chem Commun (Camb)

Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, D-48149 Münster, Germany.

Published: January 2010


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Article Abstract

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.

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http://dx.doi.org/10.1039/b920793gDOI Listing

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