Nano-zero-valent iron (nZVI) is commonly used as a reactive material for trichloro-ethylene (TCE) remediation in groundwater systems, and the long-term removal capacity serves as a critical indicator for evaluating the material efficacy. In this study, a novel sustained-release iron-carbon composite (BC@nZVI-βCD) was synthesized by the integration of biochar (BC) matrix and β-cyclodextrin (βCD) encapsulation, and the materials before and after modification were analyzed by various characterization methods. Subsequently, the kinetics of TCE removal by different materials were investigated, and the sustained-release properties of BC@nZVI-βCD were explored by batch and column experiments.
View Article and Find Full Text PDFMicrobial exopolysaccharides (EPS) exhibit high viscosity, offering significant potential for reducing soil porosity. In this paper, a kind of producing EPS was selected and its chemical and physical properties, including the morphology, molecular weight, monosaccharide composition, structure, and rheological properties, were studied. Subsequently, the effect of EPS on soil porosity was investigated by the permeability coefficient and X-ray computed tomography (X-CT), and the mechanism by which EPS reduced soil porosity was elucidated.
View Article and Find Full Text PDFZero-valent iron (ZVI) coupled with biostimulation is recognized as one of the most promising and effective dechlorination methods for chlorinated hydrocarbons in groundwater. However, the heterogeneity of the aquifer environment may affect the dechlorination efficiency of the coupled systems, and the underlying mechanisms remain unclear. In this study, we systematically explored the effect and potential mechanism of sulfate (SO) on the removal of 1,1,2-trichloroethane (1,1,2-TCA) by the coupled ZVI and biostimulation.
View Article and Find Full Text PDFOncolytic viruses (OVs) hold promise for cancer treatment. However, the antitumor efficacy is limited. Microbiota plays a pivotal role in cancer treatment and its impact on oncolytic virotherapy is unknown.
View Article and Find Full Text PDFBiodegradation
February 2025
Vapor intrusion (VI) happens when volatile organic compounds (VOCs) migrate from subsurface sources into buildings, harming indoor air quality and occupants' health. To investigate the migration and biodegradation of volatile organic compounds (VOCs) originating from subsurface sources, a soil column experiment was performed. In this experiment, high-concentration vapor from the liquid phase of toluene was steadily released into silty sand soil, aiming to simulate the conceptual model of a specific site.
View Article and Find Full Text PDFSci Total Environ
January 2025
The ferrate(VI) ion is a green, versatile oxidant employed eliminate organic contaminants. Research on the degradation of saturated chlorinated hydrocarbons such as 1,2,3-trichloropropane (1,2,3-TCP), by Fe(VI) is limited. In this study, we investigated the degradation of 1,2,3-TCP by Fe(VI).
View Article and Find Full Text PDFEnviron Technol
January 2025
nZVI has attracted much attention in the remediation of contaminated soil and groundwater, but the application is limited due to its aggregation, poor stability, and weak migration performance. The biological CaCO was used as the carrier material to support nZVI and solved the nZVI agglomeration, which had the advantages of biological carbon fixation and green environmental protection. Meanwhile, the distribution of nZVI was characterised by SEM-EDS and TEM carefully.
View Article and Find Full Text PDFMitigating the adverse effects of stressful environments on crops and promoting plant recovery in contaminated sites are critical to agricultural development and environmental remediation. Iron-based nanomaterials (Fe NMs) can be used as environmentally friendly nano-fertilizer and as a means of ecological remediation. A meta-analysis was conducted on 58 independent studies from around the world to evaluate the effects of Fe NMs on plant development and antioxidant defense systems in stressful environments.
View Article and Find Full Text PDFAdv Sci (Weinh)
April 2024
Cholesterol metabolism has important roles in maintaining membrane integrity and countering the development of diseases such as obesity and cancers. Cancer cells sustain cholesterol biogenesis for their proliferation and microenvironment reprograming even when sterols are abundant. However, efficacy of targeting cholesterol metabolism for cancer treatment is always compromised.
View Article and Find Full Text PDFIn situ anoxic bioremediation is a sustainable technology to remediate PAHs contaminated soils. However, the limited degradation rate of PAHs under anoxic conditions has become the primary bottleneck hindering the application of this technology. In this study, coupled low-temperature thermally treatment (<50 °C) and EA biostimulation was used to enhance PAH removal.
View Article and Find Full Text PDFDirect electron transfer and the involvement of atomic hydrogen (H) are considered the main mechanisms for reductive dechlorination promoted by nano zero-valent iron (nZVI) supported on highly conductive carbon. It is still unclear how precisely H, the specific surface area, and the electrochemical characteristics contribute to biochar supported nano zero-valent iron (BC-nZVI) activity in chlorinated hydrocarbon contaminant removal. In this study, a range of BC-nZVIs were prepared by a liquid-phase reduction process, and the contributions of specific surface area and electrochemical performance to H generation and electron transfer have been assessed.
View Article and Find Full Text PDFParasit Vectors
October 2023
Background: Aedes albopictus is an invasive vector of serious Aedes-borne diseases of global concern. Habitat management remains a critical factor for establishing a cost-effective systematic strategy for sustainable vector control. However, the community-based characteristics of Ae.
View Article and Find Full Text PDFSignal Transduct Target Ther
May 2023
Continuous de novo fatty acid synthesis is required for the biosynthetic demands of tumor. FBXW7 is a highly mutated gene in CRC, but its biological functions in cancer are not fully characterized. Here, we report that FBXW7β, a FBXW7 isoform located in the cytoplasm and frequently mutated in CRC, is an E3 ligase of fatty acid synthase (FASN).
View Article and Find Full Text PDFChromodomain helicase DNA binding protein (CHD) family plays critical roles in regulating gene transcription. The family is linked to cancer disease, but the family member's role in tumorigenesis remains largely unknown. Here, we report that CHD6 is highly expressed in colorectal cancer (CRC).
View Article and Find Full Text PDFThe proportion of activated persulfate (PS) oxidation technology in the remediation of domestic organic contaminated sites has increased every year, and the potential corrosion risk of site reuse caused by residual oxidants and by-products has also attracted the attention of researchers. In this work, the potential corrosion degree such as the mass reduction rate and surface crack width of standard iron flakes under different conditions, including with different PS dosages and release times, was monitored quantitatively over a long period, and the corresponding corrosion risk was quantitatively assessed. The results showed that when n (NaSO):n (PAHs) increased from 5:1 to 100:1, the higher the oxidizer dosage, the more severe the corrosion weight loss and surface crack width, indicating that the oxidizer dosage was positively correlated with the potential corrosion risk.
View Article and Find Full Text PDFBackground: The deep sea harbors the majority of the microbial biomass in the ocean and is a key site for organic matter (OM) remineralization and storage in the biosphere. Microbial metabolism in the deep ocean is greatly controlled by the generally depleted but periodically fluctuating supply of OM. Currently, little is known about metabolic potentials of dominant deep-sea microbes to cope with the variable OM inputs, especially for those living in the hadal trenches-the deepest part of the ocean.
View Article and Find Full Text PDFThe quality of agricultural soils is important for agricultural production and food safety. The contamination of agricultural soils by heavy metal(loid)s (HMs) has aroused global attention. Fifty-two topsoil samples with 8 HMs were gathered to assess the health risks of farmland soil in Huairou District, Beijing.
View Article and Find Full Text PDFMar Life Sci Technol
February 2022
Unlabelled: Hadal trenches are the least explored marine habitat on earth. Archaea has been shown to be the dominant group in trench sediments. However, the activity potentials and detailed diversity of these communities as well as their inter-trench variations are still not known.
View Article and Find Full Text PDFMicrobial degradation of organic matter along the vertical profile of the water column is a major process driving the carbon cycle in the ocean. Pseudoalteromonas has been identified as a dominant genus in pelagic marine environments worldwide, playing important roles in the remineralization of organic carbon. However, the current understanding of Pseudoalteromonas was mainly based on shallow water populations or cultivated species.
View Article and Find Full Text PDFHuan Jing Ke Xue
March 2021
A life cycle conceptual site model (LC-CSM) can represent the actual spatial distribution and migration of pollution of a site very accurately and be beneficial in supporting decisions for accurate site remediation or risk management. A volatile chlorinated hydrocarbon contaminated site in the Beijing-Tianjin-Hebei region was chosen as the study case. LC-CSMs were established following the site assessment, preliminary investigation, detailed investigation, and supplementary investigation of each stage.
View Article and Find Full Text PDFFront Microbiol
July 2020
Surprisingly high rates of microbial respiration have recently been reported in hadal trench sediment, yet the potentially active microorganisms and specific microbe-microbe relationships in trench sediment are largely unknown. We investigated the bulk and active prokaryotic communities and co-occurrence interactions of different lineages in vertically sectioned sediment cores taken from the deepest points of the Mariana and Mussau Trenches. Analysis on species novelty revealed for the first time the high rate of novel lineages in the microbial communities of the hadal trenches.
View Article and Find Full Text PDFEnviron Geochem Health
January 2021
Soil pollution at industrial sites is an important issue in China and in most other regions of the world. The accurate prediction of the spatial distribution of pollutants at contaminated industrial sites is a requirement for the development of most soil remediation strategies, and is commonly performed using spatial interpolation methods. However, significant and abrupt variations in the spatial distribution of pollutants decrease prediction accuracy.
View Article and Find Full Text PDFBr J Cancer
September 2020
An amendment to this paper has been published and can be accessed via a link at the top of the paper.
View Article and Find Full Text PDFBackground: Cancer stem cells (CSCs) are responsible for tumour initiation, metastasis and recurrence. However, the mechanism of CSC formation, maintenance and expansion in colorectal cancer (CRC) remains poorly characterised.
Methods: The role of COP9 signalosome subunit 6 (CSN6) in regulating cancer stemness was evaluated by organoid formation and limited dilution analysis.
Biochar has a wide range of feedstocks, and different feedstocks often resulted in different properties, such as element distribution and heavy metal immobilization performance. In this work, batch experiments were conducted to assess the effectiveness of biochar pyrolyzed from kitchen waste (KWB), corn straw (CSB), and peanut hulls (PHB) on immobilization of Cd and Pb in contaminated soil by planting swamp cabbage (Ipomoea aquatica Forsk.) with a combination of toxicological and physiological tests.
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