Nanoconfined Catalysts for Persulfate-Based Fenton-Like Oxidation: Mechanisms, Selectivity, and Environmental Applications.

Persulfate (PS)-based Fenton-like advanced oxidation processes (AOPs) have emerged as promising strategies for the degradation of emerging pollutants. Nevertheless, their practical deployment remains hindered by low PS utilization efficiency, poorly controlled generation of reactive species, and limited catalyst durability. Nanoconfinement engineering has emerged as a powerful strategy to overcome these limitations by tailoring the catalytic microenvironment at the nanoscale.

Light-regulated dentification and dissimilatory nitrate reduction by nano-bio electric syntrophic consortium.

Microbial-oriented nitrogen recycling is a vital strategy for nitrogen pollution control in the treatment of low C/N wastewater. However, the deficient electron donors in water body limits the reactive nitrogen recovery. Herein, we design a nano-bio electric syntrophic consortium for light-regulated dentification and dissimilatory nitrate reduction to ammonium (DNRA) without organic carbon sources input.

Bio-derived carboxymethyl cellulose-graft-gallic acid antiscalant with remarkable antibacterial activity for reverse osmosis scaling and biofouling control.

Reverse osmosis (RO) system, extensively utilized in desalination process, faced multiple challenges of various membrane fouling, including scaling and biofouling. The development of multifunctional, environmentally benign antiscalants presents a promising avenue to address these issues. In this study, a series of carboxymethyl cellulose-graft-gallic acid (CMC-g-GA) polymers were prepared by varying the mass ratio of carboxymethyl cellulose to gallic acid (GA), employed for the inhibition of calcium sulphate scale and bacteria.

A synergistic approach integrating potassium ferrate oxidation with polyacrylamide flocculation to enhance sludge dewatering and its mechanisms.

Sludge dewatering is a critical phase in sludge treatment and disposal, significantly impacting storage, transportation, and subsequent handling. This study introduces an innovative approach combining potassium ferrate (PF) oxidation and polyacrylamide (PAM) flocculation to synergistically enhance sludge dewatering efficiency. PF disrupts EPS and releases bound water, while PAM restores floc structure, addressing the limitations of standalone oxidation.

Membrane fouling mechanisms in the presence of microplastics and organic matter: The unexpected mitigating role of Ca.

Ultrafiltration (UF) is demonstrated to be highly effective in the removal of microplastics (MPs), but the presence of coexisting foulants introduces significant uncertainties into the associated membrane fouling behaviors. In this study, membrane fouling mechanisms were investigated when MPs, represented by polystyrene (PS), coexisted with typical organic foulants (sodium alginate, SA) and inorganic ions (Ca). Fouling tests revealed that the order of Ca addition significantly impacted the fouling behavior of the SA-PS combined foulants.

A synergistic approach combining computational fluid dynamics simulation with hydrolysis-acidification for dye wastewater treatment.

Wastewater treatment is effectively conducted using anaerobic biological methods. Nevertheless, the efficiency of these methods can be hindered by challenges like short-circuits and dead zones, particularly in treating persistent contaminants. This work utilized computational fluid dynamics (CFD) simulations to enhance water distribution, ensuring uniform interactions between solid and liquid phases, and thus mitigating issues related to short-circuits and dead zones.

Enhanced sludge dewatering using a novel synergistic iron/peroxymonosulfate-polyacrylamide method.

In the sludge dewatering process, a formidable challenge arises due to the robust interactions between extracellular polymeric substances (EPS) and bound water. This study introduces a novel, synergistic conditioning method that combines iron (Fe)/peroxymonosulfate (PMS) and polyacrylamide (PAM) to significantly enhance sludge dewatering efficiency. The application of the Fe/PMS-PAM conditioning method led to a substantial reduction in specific filtration resistance (SFR) by 82.

Predicting thermodynamic adhesion energies of membrane fouling in planktonic anammox MBR via backpropagation neural network model.

Predicting thermodynamic adhesion energies was a critical strategy for mitigating membrane fouling. This study utilized a backpropagation (BP) neural network model to predict the thermodynamic adhesion energies associated with membrane fouling in a planktonic anammox MBR. Acid-base (ΔG), electrostatic double layer (ΔG), and Lifshitz-van der Waals (ΔG) energies were selected as output variables, the training dataset was collected by the advanced Derjaguin-Landau-Verwey-Overbeek (XDLVO) method.

Durable Nano-Flower Structured Foam Coupled with Electrically-Driven in Situ Aeration Enable High-Flux Oil/Water Emulsion Separation with Dynamic Antifouling Ability.

The conventional membranes used for separating oil/water emulsions are typically limited by the properties of the membrane materials and the impact of membrane fouling, making continuous long-term usage unachievable. In this study, a filtering electrode with synchronous self-cleaning functionality is devised, exhibiting notable antifouling ability and an extended operational lifespan, suitable for the continuous separation of oil/water emulsions. Compared with the original Ti foam, the in situ growth of NiTi-LDH (Layered double hydroxide) nano-flowers endows the modified Ti foam (NiTi-LDH/TF) with exceptional superhydrophilicity and underwater superoleophobicity.

Innovative treatment of industrial effluents through combining ferric iron and attapulgite application.

The escalation of industrial activities has escalated the production of pharmaceutical and dyeing effluents, raising significant environmental issues. In this investigation, a hybrid approach of Fenton-like reactions and adsorption was used for deep treatment of these effluents, focusing on effects of variables like hydrogen peroxide concentration, catalyst type, pH, reaction duration, temperature, and adsorbent quantity on treatment effectiveness, and the efficacy of acid-modified attapulgite (AMATP) and ferric iron (Fe(III))-loaded AMATP (Fe(III)-AMATP) was examined. Optimal operational conditions were determined, and the possibility of reusing the catalysts was explored.

An efficient solution based on the synergistic effects of nickel foam in NiFe-LDH nanosheets for oil/water separation.

Efficient oil-water separation has always been a research hotspot in the field of environmental studies. Employing a one-step hydrothermal approach, NiFe-layered double hydroxides (LDH) nanosheets were synthesized on nickel foam substrates. The resulting NiFe-LDH/NF membrane exhibited rejection rates exceeding 99% across six diverse oil-water mixtures, concurrently demonstrating a remarkable ultra-high flux of 1.

Mg addition: Unlocking optimized treatment performance and anti-fouling property in microalgal-bacterial membrane bioreactors.

While microalgal-bacterial membrane bioreactors (microalgal-bacterial MBRs) have risen as an important technique in the realm of sustainable wastewater treatment, the membrane fouling caused by free microalgae is still a significant challenge to cost-effective operation of the microalgal-bacterial MBRs. Addressing this imperative, the current study investigated the influence of magnesium ion (Mg) addition on the biological dynamics and membrane fouling characteristics of the laboratory-scale submerged microalgal-bacterial MBRs. The results showed that Mg, important in augmenting photosynthetic process, yielded a biomass concentration of 2.

Thiol-Ene Click Reaction in Constructing Liquid Separation Membranes for Water Treatment.

In the evolving landscape of water treatment, membrane technology has ascended to an instrumental role, underscored by its unmatched efficacy and ubiquity. Diverse synthesis and modification techniques are employed to fabricate state-of-the-art liquid separation membranes. Click reactions, distinguished by their rapid kinetics, minimal byproduct generation, and simple reaction condition, emerge as a potent paradigm for devising eco-functional materials.

Harnessing diurnal dynamics: Deciphering the interplay of light cycles on algal-bacterial membrane bioreactors.

Light profoundly modulates the algal-bacterial membrane bioreactor (algal-bacterial MBR) performance. Yet, its outdoor deployment grapples with the inherent diurnal cycle of sunlight, engendering suboptimal light conditions. The adaptability of such systems to these fluctuating light conditions and their implications for practical outdoor applications remained an under-explored frontier.

Mxenes for membrane separation: from fabrication strategies to advanced applications.

Transition metal carbides/nitrides/carbonitrides, commonly referred to as MXenes, have gained widespread attention since their discovery in 2011 as a promising family of two-dimensional (2D) materials. Their impressive chemical, electrical, thermal, mechanical, and biological properties have fueled a surge in research focused on the synthesis and application of MXenes in various fields, including membrane-based separation. By engineering the materials and membrane structures, MXene-based membranes have demonstrated remarkable separation performance and added functionalities, such as antifouling and photocatalytic properties.

Optimizing aeration intensity to enhance self-flocculation in algal-bacterial symbiosis systems.

Effectuating optimal wastewater treatment via algae-bacterial symbiosis (ABS) systems necessitates the precise selection of aeration intensity. This study pioneers an in-depth investigation into the interplay of aeration intensity on the microalgal-bacterial consortia's self-flocculation efficacy and the overall treatment performance within ABS systems. The research provides evidence for a direct association between aeration intensity and biomass proliferation, indicating enhanced pollutant removal efficiency with escalated intensities (1.

Superior performance of a membrane bioreactor through innovative in-situ aeration and structural optimization using computational fluid dynamics.

The optimization of membrane bioreactors (MBRs) involves a critical challenge in structural design for mitigation of membrane fouling. To address this issue, a three-dimensional computational fluid dynamics (CFD) model was utilized in this study to simulate the hydrodynamic characteristics of a flat sheet (FS) MBR. The optimization of the membrane module configuration and operating conditions was performed by investigating key parameters that altered the shear stress and liquid velocity.

Quantifying interfacial interactions for improved membrane antifouling: A novel approach using triangulation and surface element integration method.

To gain a thorough understanding of interfacial behaviors such as adhesion and flocculation controlling membrane fouling, it is necessary to simulate the actual membrane surface morphology and quantify interfacial interactions. In this work, a new method integrating the rough membrane morphology reconstruction technology (atomic force microscopy (AFM) combining with triangulation technique), the surface element integration (SEI) method, the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory, the compound Simpson's approach, and the computer programming was proposed. This new method can exactly mimic the real membrane surface in terms of roughness and shape, breaking the limitation of previous fractal theory and Gaussian method where the simulated membrane surface is only statistically similar to the real rough surface, thus achieving a precise description of the interfacial interactions between sludge foulants and the real membrane surface.

Novel thermodynamic mechanisms of co-conditioning with polymeric aluminum chloride and polyacrylamide for improved sludge dewatering: A paradigm shift in the field.

This study investigated the combined effects of polymeric aluminum chloride (PAC) and polyacrylamide (PAM) on sludge dewatering, aiming to unveil underlying mechanisms. Co-conditioning with 15 mg g PAC and 1 mg g PAM achieved optimal dewatering, reducing specific filtration resistance (SFR) of co-conditioned sludge to 4.38 × 10 mkg, a mere 48.

3D printing titanium dioxide-acrylonitrile-butadiene-styrene (TiO-ABS) composite membrane for efficient oil/water separation.

The oily water treatment is becoming one of the hottest topics due to that increase of offshore oil transportation and the various accident oil leakages. In this study, a functional TiO-ABS composite membrane was generated through the three-dimensional (3D) printing strategy for the first time and was conducted to simulated oily water treatment. The TiO-ABS composite membrane demonstrated a significant promotion in hydrophilicity and oleophobicity which were evidenced by the water contact angle of 14.

Mitigation of protein fouling by magnesium ions and the related mechanisms in ultrafiltration process.

Although protein is an important membrane foulant in the water body that may be significantly affected by the coexisting common cation magnesium (Mg), the effect of Mg on protein fouling is rarely reported. In this context, this study selected bovine serum albumin (BSA) as the model foulant, and investigated its fouling characteristics at different Mg concentrations (0-100 mM). Filtration tests showed that the protein fouling can be significantly mitigated by adding Mg, and the specific filtration resistance (SFR) of pure BSA (3.

Molecular-level insights into the mitigation of magnesium-natural organic matter induced ultrafiltration membrane fouling by high-dose calcium based on DFT calculation.

While magnesium cation (Mg) universally coexists with natural organic matter (NOM) in the water environment, influence of Mg on NOM fouling in membrane filtration process is still unclear. This work was therefore performed to investigate effects of Mg on NOM (sodium alginate (SA) as a model substance) fouling and role of Ca in mitigating fouling from Mg in the ultrafiltration (UF) water treatment process. Filtration tests showed two interesting fouling phenomena: (1) membrane fouling caused by combination of Mg and SA maintained at a high value with the increased Mg concentration; (2) the high fouling property of Mg can be significantly improved by the prominent addition of calcium cation (Ca).

Molecular insights into impacts of EDTMPA on membrane fouling caused by transparent exopolymer particles (TEP).

While ethylenediamine tetramethylenephosphonic acid (EDTMPA) has been emerged as a stronger chelating agent than ethylene diamine tetraacetic acid (EDTA) for fouling mitigation, and transparent exopolymer particles (TEP) is a major foulant in membrane-based water treatment process, effects of EDTMPA on TEP fouling and the underlying mechanism have been not yet studied. In this study, Flory-Huggins lattice theory was combined with density functional theory (DFT) technology to explore this subject at molecular level. Filtration experiments showed a unimodal pattern of specific filtration resistance (SFR) of TEP sample with Ca concentration in range of 0-3 mM.

Mechanistic insights into Ca-alginate gel-associated membrane fouling affected by ethylene diamine tetraacetic acid (EDTA).

While transparent exopolymer particles (TEP) is a major foulant, and ethylene diamine tetraacetic acid (EDTA) is a strong chelating agent frequently used for fouling mitigation in membrane-based water treatment processes, little has been known about TEP-associated membrane fouling affected by EDTA. This work was performed to investigate roles of EDTA addition in TEP (Ca-alginate gel was used as a TEP model) associated fouling. It was interestingly found that, TEP had rather high specific filtration resistance (SFR) of 2.

Effects of polysaccharides' molecular structure on membrane fouling and the related mechanisms.

Fouling behaviors of polysaccharides vary with their structure, while the mechanisms underlying this phenomenon remain unexplored. This work was carried out to explore the thermodynamic fouling mechanisms of polysaccharides with different structure. Carrageenan and xanthan gum were selected as the model polysaccharides with structure of straight and branch chains, respectively.