Vegetation-Driven Changes in Soil Salinity Ions and Microbial Communities Across Tidal Flat Reclamation.

Soil microbes play a vital role in tidal flat ecosystems but are highly susceptible to disturbances from land reclamation. This study investigated the dynamics of bacterial communities and their environmental drivers across a 50-year reclamation chronosequence under three vegetation types (bare flats, reed beds, and rice fields). The results showed that, after 50 years of reclamation, total dissolved salts decreased significantly in vegetated zones, particularly in rice fields, where Cl dropped by 54.

Straw amendment decreased Cd accumulation in Solanum lycopersicum due to enhanced root functional traits under low-P supply.

Manipulating root functional traits related to phosphorus (P) mobilization and acquisition by using the optimum rate of synthetic P fertilizer coupled with straw addition is a promising option for improving nutrient-use efficiency in agriculture. How such practices influence soil cadmium (Cd) fractions and plant Cd accumulation remains unknown. We conducted two field trials: exp.

Interfacial Charge Transfer Regulates Photoredox Catalysis.

Photoredox catalytic processes offer the potential for precise chemical reactions using light and materials. The central determinant is identified as interfacial charge transfer, which simultaneously engenders distinctive behavior in the overall reaction. An in-depth elucidation of the main mechanism and highlighting of the complexity of interfacial charge transfer can occur through both diffusive and direct transfer models, revealing its potential for sophisticated design in complex transformations.

Carbon-Phosphorus Coupling Governs Microbial Effects on Nutrient Acquisition Strategies by Four Crops.

Plants adjust root morphological and/or exudation traits in response to phosphorus (P) mobilization mediated by microorganisms. We hypothesized that straw application coupled with P fertilization would influence microbial P and then root nutrient-acquisition strategies related to crop growth. Root morphological (length and average diameter) and exudation traits (acid phosphatase and carboxylates) of , , and in response to microbial P dynamics were characterized in no-P and P-fertilized soil with/without straw addition.

Highly Effective Photocatalytic Radical Reactions Triggered by a Photoactive Metal-Organic Framework.

On account of their inherent reactive properties, radical reactions play an important role in organic syntheses. The booming photochemistry provides a feasible approach to trigger the generation of radical intermediates in organic reaction processes. Thus, developing effective photocatalysts becomes the key step in radical reactions.

High Enhancement in Proton Conductivity by Incorporating Sulfonic Acids into a Zirconium-Based Metal-Organic Framework via "Click" Reaction.

Taking a robust zirconium-based metal-organic framework, UiO-66, as a prototype, functional postmodification via the versatile Cu(I)-catalyzed azide-alkyne "click" reaction was carried out, and sulfonic acid groups were successfully grafted into its skeleton. Characterizations revealed that the MOF network was still well maintained after being treated by "clicked" modification. Investigations by electrochemical impedance spectroscopy measurements revealed that its proton conductivity increases exponentially up to 8.

Incorporating Photochromic Triphenylamine into a Zirconium-Organic Framework for Highly Effective Photocatalytic Aerobic Oxidation of Sulfides.

A zirconium-based metal-organic framework (MOF) was successfully constructed solvothermal assembly of a triphenylamine-based tricarboxylate ligand and Zr(IV) salt, the structure simulation of which revealed that it possesses a two-dimensional layered framework with a relatively rare dodecnuclear Zr cluster as the inorganic building unit. The inherent photo-responsive property derived from the incorporated photochromic triphenylamine groups combined with its high stability makes the constructed MOF an efficient heterogeneous photocatalyst for the oxidation of sulfides, which is a fundamentally important reaction type in both environmental and pharmaceutical industries. The photocatalytic activity of the constructed MOF was first investigated under various conditions with thioanisole as a representative sulfide substrate.

Effect of nitrogen application rate on soil fungi community structure in a rice-fish mutualistic system.

Rice-fish mutualistic production systems rationalise the use of water and soil resources in an improved approach to sustainable food production. However, drivers of fungi community structure in paddy soil, including effects of nitrogen (N) application rate, are unclear in these systems. Here, we assessed soil fungi community and soil physicochemical responses in paddy soil to contrasting rates of N application in a rice-fish system.

In Situ Metal-Assisted Ligand Modification Induces Mn Cluster-to-Cluster Transformation: A Crystallography, Mass Spectrometry, and DFT Study.

Dehydration of (S,S)-1,2-bis(1H-benzo[d]imidazol-2-yl)ethane-1,2-diol (H L) to (Z)-1,2-bis(1H-benzo[d]imidazol-2-yl)ethenol) (H L') was found to be metal-assisted, occurs under solvothermal conditions (H O/CH OH), and leads to [Mn (H L) Cl ]Cl ⋅5 H O⋅5 CH OH (Mn L ) and [Mn (H L') (μ -OH)]Cl⋅4 CH OH⋅H O (Mn L' ), respectively. Their structures were determined by single-crystal XRD. Extensive ESI-MS studies on solutions and solids of the reaction led to the proposal consisting of an initial stepwise assembly of Mn L from the reactants via [MnL] and [Mn L ] below 80 °C, and then disassembly to [MnL] and [MnL ] followed by ligand modification before reassembly to Mn L' via [MnL'], [MnL' ], and [Mn L' ] with increasing solvothermal temperature up to 140 °C.

Neighbouring plants modify maize root foraging for phosphorus: coupling nutrients and neighbours for improved nutrient-use efficiency.

Nutrient distribution and neighbours can impact plant growth, but how neighbours shape root-foraging strategy for nutrients is unclear. Here, we explore new patterns of plant foraging for nutrients as affected by neighbours to improve nutrient acquisition. Maize (Zea mays) was grown alone (maize), or with maize (maize/maize) or faba bean (Vicia faba) (maize/faba bean) as a neighbour on one side and with or without a phosphorus (P)-rich zone on the other in a rhizo-box experiment.

Increased planting density of Chinese milk vetch () weakens phosphorus uptake advantage by rapeseed () in a mixed cropping system.

Neighbouring plants can affect plant growth through altering root morphological and physiological traits, but how exactly root systems respond to neighbouring plants with varied density, determining nutrient uptake and shoot growth is poorly understood. In a pot-based experiment, rapeseed was grown alone (single rapeseed), or mixed with 3, 6, or 15 Chinese milk vetch plants. As controls, monocropped Chinese milk vetch was grown at the same planting density, 3, 6, or 15 plants per pot.

Thermally Induced trans-to-cis Isomerization and Its Photoinduced Reversal Monitored using Absorption and Luminescence: Cooperative Effect of Metal Coordination and Steric Substituent.

For ethene derivatives with large groups the cis-isomer is often quite unstable and unavailable. Herein, we report an exception of two stable coordination complexes, (cis-L)ZnCl , starting from trans-1,2-bis(1-R-benzo[d]imidazol-2-yl)ethene (R=H, L1; R=CH , L2) ligands under solvothermal condition (T ≥140 °C). Using the intensity of the absorption and luminescence spectra as probes we proposed its progressive cis-to-trans reversal upon irradiation with UV light, which was confirmed by powder X-ray diffraction (PXRD).

A model to predict the incidence of allergic rhinitis based on meteorological factors.

Meteorological factors have been shown to affect the physiology, distribution, and amounts of inhaled allergens. The aim of this study was to develop a model to predict the trends for onset of allergic rhinitis (AR) patients. A total of 10,914 consecutive AR outpatients were assessed for the number of daily patient visits over a period of 4 years.

Incidence of allergic rhinitis and meteorological variables: Non-linear correlation and non-linear regression analysis based on Yunqi theory of chinese medicine.

Objective: To analyze the correlations between the incidence of allergic rhinitis (AR) and meteorological variables of previous periods, so as to establish non-linear prediction equations of AR in Beijing area.

Methods: AR patients (10,478 cases) collected from Beijing Tongren Hospital during 2007-2010 and meteorological data (including daily average temperature, daily maximum temperature, daily minimum temperature, daily relative humidity, daily average vapor pressure, daily dew point temperature, daily precipitation, daily average wind speed, sea level pressure, and degree of comfort) collected from Beijing Municipal Meteorological Observatory in the same periods were used for the analysis. Non-linear correlation and regression were adopted to analyze the relationship between AR incidence and meteorological variables of former six-qi stage which was defined according to Yunqi theory of Chinese medicine.

Increased soil phosphorus availability induced by faba bean root exudation stimulates root growth and phosphorus uptake in neighbouring maize.

Root growth is influenced by soil nutrients and neighbouring plants, but how these two drivers affect root interactions and regulate plant growth dynamics is poorly understood. Here, interactions between the roots of maize (Zea mays) and faba bean (Vicia faba) are characterized. Maize was grown alone (maize) or with maize (maize/maize) or faba bean (maize/faba bean) as competitors under five levels of phosphorus (P) supply, and with homogeneous or heterogeneous P distribution.

Relationship between haze and acute cardiovascular, cerebrovascular, and respiratory diseases in Beijing.

Haze is an atmospheric phenomenon in which dry particulate pollutants obscure the sky. Haze has been associated with chronic diseases, but its relationship with acute diseases is less clear. We aimed to determine the association between haze and acute cardiovascular, cerebrovascular, and respiratory diseases, in order to determine the influence of haze on human health.

[Grading forecast research for pathogenesis of allergic rhinitis directed by meteorological elements].

Objective: To analyze the correlation between meteorological factors and onset of allergic rhinitis (AR), and to establish the prediction of AR epideminlogical trend.

Methods: According to skin prick test (SPT) data of AR from Beijing Tongren Hospital and meteorological data of Beijing Observatory (2007 -2010) , analyzed the relationship between meteorological factors and onset in patients with AR. To analyze the probability distribution of onset in AR patients, and establish the grade of AR epideminlogical trend index.

[Correlation between symptoms of pollen allergic rhinitis and pollen grain spreading in summer and autumn].

Objective: To analyze the correlation between airborne pollen concentrations and symptoms in patients with pollen allergic rhinitis.

Methods: Durhum sampler was used to collect the pollen concentration and species from June to September in 2011. The clinical skin prick test (SPT) data were analyzed.

The association between daily outpatient visits for allergic rhinitis and pollen levels in Beijing.

To investigate the effects of aerosol pollen on human health, we carried out a time-series analysis of daily general practitioner consultations for allergic rhinitis (AR) in Beijing. The objective of this study was to assess the possible effects of pollen on clinic visits for allergic rhinitis in Beijing during the pollen season. We found a strong association between the concentration of pollen in ambient air and the number of consultations for allergic rhinitis.

Correlation analysis for the attack of respiratory diseases and meteorological factors.

Objective: To investigate the relationship between respiratory diseases onset and the meteorological factors in the same period and in a specific environment. METHODS METHODS: By using the data of daily incidence of respiratory diseases obtained from Dongzhimen Hospital Affiliated to Beijing University of Chinese Medicine from January 1, 1998 to December 31, 2007, and the data of 16 items of meteorological factors (such as the average, maximum, and minimum temperatures, etc., including meteorological factors derived) obtained from the Beijing Municipal Meteorological Observatory, mathematical statistical methods were applied to achieve the non-linear correlation analysis, or the correlation test, between the incidence of respiratory diseases and the time-related meteorological factors.

[The effect of Hongjingtian (Gadol) injection on cardiac hemodynamics and myocardial oxygen consumption of dogs].

Objective: To study the effect of Hongjingtian (Gadol) injection on cardiac hemodynamics and myocardial oxygen consumption for analyzing its underlying mechanism in the treatment of coronary heart disease.

Method: A total of 20 dogs anesthetized with pentobarbital sodium (30 mg x kg(-1), i.v.