98%
921
2 minutes
20
Wetting phenomena are relevant in several technological applications, particularly those involving hydrophobic or hydrophilic surfaces. Many substrates support multiple wetting states depending on surface conditions or droplet history-a behavior known as metastability. This feature is crucial both for its theoretical complexity and for its relevance in practical applications that rely on controlling metastable states. While several experimental and computational techniques have been developed to study metastability, they tend to be complex or computationally expensive. In this work, we introduce an alternative approach based on concepts from active matter physics. We investigate the wetting behavior of a droplet placed on a pillared surface using a 3-state cellular Potts model with a polarity term that mimics a self-propelled droplet. Applying this model to a pillared substrate with known metastable wetting states, we demonstrate that increasing activity enables the droplet to traverse free energy barriers, explore consecutive metastable states, and eventually suppress metastability entirely. Our results show that activity reduces the disparity between dry and wet states and provides a reliable framework for identifying and quantifying metastability through contact angle measurements.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/d5sm00492f | DOI Listing |
Proc Natl Acad Sci U S A
September 2025
Soft Matter Sciences and Engineering, CNRS, École supérieure de Physique et de Chimie Industrielles de la Ville de Paris, Université Paris Sciences et Lettres, Sorbonne Université, Paris 75005, France.
The sliding motion of aqueous droplets on hydrophobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been attributed to ions or electrons ripped off from the liquid drop. However, the dynamics and exact physicochemical nature of these surface-trapped charges remains poorly explored.
View Article and Find Full Text PDFLangmuir
September 2025
Key Laboratory of Unconventional Oil & Gas Development (China University of Petroleum (East China)), Ministry of Education, Qingdao 266580, China.
Surfactant-enhanced spontaneous imbibition is a proven method of enhancing oil recovery from shale reservoirs. However, a significant knowledge gap concerning the impact of clay minerals on surfactant-enhanced imbibition in shale reservoirs remains. Therefore, this study first analyzed the mineral composition and pore structure of the shale reservoirs.
View Article and Find Full Text PDFACS Nano
September 2025
State Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membrane, Nanjing Tech University, Nanjing 210009, China.
Airborne pathogens and pollution control typically necessitate multiple membranes, each specializing in efficient aerosol filtration, moisture regulation, or antimicrobial protection. Integrating all these functions into a single membrane is highly advantageous but remains inherently challenging due to material incompatibility and inevitable performance trade-offs. Here, we present a photoactive Janus nanofibrous membrane for highly efficient air purification, engineered via sequential electrospinning.
View Article and Find Full Text PDFNanoscale
September 2025
School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China.
Metal matrix composites are widely employed in aerospace and marine engineering due to their excellent mechanical properties and chemical stability. However, their surfaces remain vulnerable to corrosion, icing, and mechanical wear, severely compromising long-term reliability in harsh environments. Inspired by natural superhydrophobic surfaces such as lotus leaves, functional interfaces with high water repellency and interfacial stability can be engineered through the synergistic design of hierarchical micro/nanostructures and low-surface-energy chemical modifications.
View Article and Find Full Text PDFACS Omega
September 2025
Department of Horticultural Science, Texas A&M University, College Station, Texas 77843, United States.
The limited water solubility and environmental instability of natural pesticidal compounds impede their broader agricultural use. This study reports an amphiphile-assisted nanoprecipitation method to imbibe azadirachtin-rich neem seed extract (NSE) within a glycine carrier matrix, yielding a stable nanocomposite biopesticide. The formulation, prepared using polyoxyethylene sorbitan monooleate as a stabilizer and glycine as the matrix former, followed by lyophilization, exhibited a hydrodynamic diameter of ∼8 nm when redispersed in water.
View Article and Find Full Text PDF