98%
921
2 minutes
20
We systematically investigate second-harmonic generation (SHG) in a lithium triborate (LBO) crystal by a femtosecond laser system (1030 nm, 195 fs, 30 W) with particular emphasis on back-conversion phenomena. For a selected 5 mm thick crystal, an optimal conversion efficiency of 54% is achieved at 18 W input power with beam quality factor M of 1.275 (horizontal) and 1.173 (vertical). Beyond the saturation threshold where back-conversion initiates, spectral broadening, temporal compression and beam quality deterioration emerge, accompanied by decreasing conversion efficiency. Increasing the beam diameter or reducing the crystal length effectively mitigates back-conversion phenomena. These findings establish valuable guidelines for optimizing the performance of femtosecond visible laser sources.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1364/OE.566024 | DOI Listing |
Chem Sci
September 2025
State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystals, Tianjin University of Technology Tianjin 300384 China
Nonlinear optical (NLO) crystals capable of expanding the spectral region of solid-state are of great importance for many high-tech applications, yet their rational structure design remains a great challenge because of the conflicting property requirements among second harmonic generation (SHG) response, ultraviolet (UV) cut-off edge, and birefringence. Herein, based on the chemical disubstitution of the classic NLO crystal SrBeBO (SBBO), , substituting [BO] triangles with larger π-conjugated [BO] groups and substituting high-toxic [BeO] tetrahedra with environment-friendly [AlO] tetrahedra, a new high-performance aluminoborate NLO crystal, BaAlBO, has been successfully designed and synthesized. The theoretical calculations and optical property measurements indicate that BaAlBO exhibits not only the largest SHG response among the reported aluminoborates (2.
View Article and Find Full Text PDFAdv Mater
September 2025
Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, 830011, P. R. China.
The generation of coherent deep-ultraviolet (DUV) radiation via nonlinear frequency conversion remains a major scientific and technological challenge in modern optics. To date, only a very limited number of nonlinear optical (NLO) crystals-such as KBBF, ABF, and quartz-have been experimentally demonstrated to support measurable direct second-harmonic generation (SHG) at wavelengths of 177 nm or shorter. There is a pressing need to develop alternative materials or strategies that enable efficient frequency conversion in the DUV region.
View Article and Find Full Text PDFCarbohydr Polym
November 2025
Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Campus Kulak Kortrijk, Etienne Sabbelaan 53, 8500 Kortrijk, Belgium. Electronic address:
Cellulose nanocrystals (CNCs) have emerged as promising candidates for chiroptical functional materials due to their ability to form cholesteric liquid crystals with tunable periodicity. The quality of the final cholesteric phase is influenced by the nucleation, growth and coalescence mechanism of the initial droplets, known as tactoids. Current research focuses on understanding the size and morphological transformations of these tactoids, to gain deeper insights into their dynamic behavior and, in turn, to better control the final properties of novel photonic materials.
View Article and Find Full Text PDFNpj Nanophoton
September 2025
Chair in Hybrid Nanosystems, Nanoinstitute Munich, Faculty of Physics, Ludwig-Maximilians-Universität München, Munich, Germany.
Second-order nonlinear optical processes are fundamental to photonics, spectroscopy, and information technologies, with material platforms playing a pivotal role in advancing these applications. Here, we demonstrate the exceptional nonlinear optical properties of the van der Waals crystal 3R-MoS, a rhombohedral polymorph exhibiting high second-order optical susceptibility ( ) and remarkable second-harmonic generation (SHG) capabilities. By designing high quality factor resonances in 3R-MoS metasurfaces supporting quasi-bound states in the continuum (qBIC), we first demonstrate SHG efficiency enhancement exceeding 10.
View Article and Find Full Text PDFACS Mater Lett
September 2025
Preventive and Restorative Dentistry, School of Dental Medicine, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Natural biopolymer hydrogels often suffer from relatively low moduli and an inability to maintain structure and mechanics under cyclic loading, limiting their utility in dynamic mechanical environments. Here, a cross-linked collagen cryogel scaffold was fabricated by precompression to densify the network. Following lyophilization, the porous scaffolds sustained >90% axial compressive strain with 200 cycles.
View Article and Find Full Text PDF