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This study investigates the physicochemical and microbiological properties of oily sludge from the Skikda petrochemical refinery, Algeria, to assess ecological risks and bioremediation potential. Sludge samples at different aging stages (6 months, 3 months, and fresh) were analyzed using GC-MS, FTIR, SEM-EDX, and 16S rRNA metabarcoding. Results reveal high organic matter (53-63 %), petroleum hydrocarbons (14,700-21,440 mg kg), and heavy metals (e.g., Cd, As, Cr), with toxicity increasing with sludge age. The Ecological Risk Index (ERI <40) indicates low ecological risk, though metal accumulation rises over time. Microbial analysis identified diverse communities, dominated by Proteobacteria, Firmicutes, and Bacteroidota, with hydrocarbon-degrading bacteria (Pseudomonas, Klebsiella) suggesting strong bioremediation potential. These findings provide critical insights into sludge composition and microbial dynamics, offering a foundation for cost-effective, sustainable bioremediation strategies tailored to Algerian refineries and applicable globally.
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http://dx.doi.org/10.1016/j.chemosphere.2025.144578 | DOI Listing |
Crit Rev Anal Chem
September 2025
Department of Civil Engineering, Architecture and Engineering, Northeast Petroleum University, Daqing, China.
Surfactant is usually considered the key component to form microemulsion. surfactant-based microemulsion (SBME) can also be called traditional microemulsion. It has a wide range of applications.
View Article and Find Full Text PDFJ Environ Manage
August 2025
CSIR-North East Institute of Science and Technology, Jorhat, 785006, Assam, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India. Electronic address:
Petroleum waste pollution presents a major environmental challenge, highlighting the need for sustainable and efficient remediation strategies. Bioremediation has emerged as a promising eco-friendly solution that utilizes microbial communities to degrade harmful hydrocarbons. Among various bioremediation approaches, composting is an established organic waste treatment method that has been effectively adapted for managing petroleum-contaminated sludge.
View Article and Find Full Text PDFLangmuir
August 2025
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, No. 159 Longpan Road, Nanjing 210037, PR China.
Global water security is facing unprecedented challenges, among which oil spills, illegal discharge of industrial wastewater, and uncontrolled discharge of oily wastewater from domestic sewage are particularly prominent. These sources of pollution not only lead to the continuous deterioration of water resource quality but also pose multiple threats to the ecological balance and human health and safety. In this background, the development of efficient oily wastewater separation and recycling technologies has become a key topic to be solved in the current environmental engineering field.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China.
Multifunctional superhydrophobic nanocellulose-based membranes for self-cleaning, oil/water separation, photocatalytic degradation, and anti-biofouling are in great demand for sewage treatment. This demand led to the in situ deposition of Cu-MOF micro/nanoparticles on the surface of CB membranes, followed by stearic acid (STA) modification to provide excellent superhydrophobicity, which enables effective oil/water separation, photocatalytic degradation, and anti-biofouling. The CB/Cu-MOF/STA membranes created in this manner demonstrated good superhydrophobicity with a water contact angle of 160 ± 2° and superoleophobicity with an oil contact angle of 0°.
View Article and Find Full Text PDFJ Environ Manage
September 2025
School of Chemical Engineering and Energy Technology, Dongguan University of Technology, Dongguan, 523808, China.
This study examined the influence of steel slag powder as an additive on the pyrolysis characteristics of sludge, including the activation energy of the reactions, in addition to inhibiting the escape of nitrogen-containing and sulfur-containing gases, while improving the bio-oil fraction. There were three methods used to calculate the average activation energy of sludge: Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Friedman. It can be concluded that the addition of steel slag powder accelerated sludge pyrolysis and that the kinetic modeling during the primary pyrolysis stages occurred through a reaction-level mechanism model (Fn).
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