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Tracking gas migration geochemically is more challenging than tracking oil migration due to the deficiency in biomarkers and migration tracers, traditionally restricting gas tracking to isotope fingerprinting. This highlights the need for developing new fluid interpretation workflows that maximize the value of reservoir fluid data to constrain gas migration models. Systematic analysis of reservoir PVT fluid properties from 49 wells in a complex carbonate-evaporite sequence across four adjacent Paleozoic gas fields on the eastern part of the Arabian Plate, supported by multivariate statistical analysis, enabled the tracking of gas migration. Results were used to test current basin models, differentiate fault migration from carrier migration, and evaluate the impact of migration style and dynamics on fluid properties and distributions. The first basin model invokes a very long-range migration in excess of 300 km, accumulating first in the northernmost field before spilling over to the south. The second model entails filling from the east via multiple parallel pathways. Regional northward increase in gas-oil ratio and gas maturity, concomitant with enrichment of nitrogen and carbon-13, seemingly supports the north-charging model, but on closer inspection of reservoir fluid properties, the east-charging model is favored. Multiple parallel charging along the eastern flank is reflected in parallel but overlapping fluid maturity and density segregation trends, supported by ratios of reservoir pressure to dewpoint pressure that almost double towards the drier gas in the deeper north due to increased pressurization from more-mature charges coupled with increased hydrocarbon consumption by thermochemical sulfate reduction. The observed patterns in fluid properties are contrary to what would be expected in a single southward fill-spill setting or a single accumulation in equilibrium encompassing the four fields. Migration style played a major control on gas properties and distributions, with carrier migration yielding maturity and density profiles that follow reservoir depth, supplemented in certain areas by fault migration that increased gas dryness and column height. Findings have significant implications for targeting drier gas in stratigraphic and diagenetic traps along the deeper east, particularly where downdip faults meet migration pathways. Similar workflows can be used to constrain reservoir models.
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http://dx.doi.org/10.1038/s41598-025-10508-x | DOI Listing |
RSC Adv
September 2025
Food and Drug Safety Research Center, Pharmaceutical Sciences Institute, Tabriz University of Medical Sciences Tabriz Iran.
This study focuses on developing an analytical method to efficiently extract and concentrate several adipate and phthalate plasticizers that can migrate from plastic packaging into various wound disinfectants. The study employed an approach that combined dispersive micro solid phase extraction with dispersive liquid-liquid microextraction using ZIF-4 as an adsorbent. The adsorbent was thoroughly characterized to understand its properties.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
To analyse the issues of high muzzle flame intensity and the easy migration of insensitive agents in conventional insensitive propellants, this study synthesizes modified nitrocellulose grafted with carboxymethyl potassium groups by a two-step process, starting from the molecular structure of nitrocellulose (NC), the principal component of propellants. First, the denitration reaction was performed to reduce part of the nitrate ester groups on the surface of NC to hydroxyl groups, followed by an etherification reaction to achieve directional grafting of carboxymethyl potassium groups. Compared with conventional flame retardant/insensitive systems based on nitrogen, phosphorus, or DBP (dibutyl phthalate), potassium-based functional groups exhibit superior thermal stability and environmental friendliness.
View Article and Find Full Text PDFAdv Mater
September 2025
NRC (Nanostructure Research Centre), Wuhan University of Technology, Wuhan, 430070, China.
Thermoelectric nanoplates derived from anisotropic van der Waals (vdW) materials such as BiTe are pivotal for flexible electronics and microscale thermal management. Their performance critically depends on grain boundary (GB) microstructure, but the atomic-scale mechanisms governing grain growth in these highly anisotropic systems remain elusive. This particularly concerns the competition between individual nanoplate reshaping driven by facet stabilization and collective merging at GBs.
View Article and Find Full Text PDFEnviron Res
September 2025
College of Nuclear Technology and Automation Engineering, Chengdu University of Technology, Chengdu 610059, Sichuan,P.R.China; Applied Nuclear Technology in Geosciences Key Laboratory of Sichuan Province, Chengdu University of Technology, Chengdu 610059, P.R.China.
Naturally occurring radioactive materials (NORM) are present in waste generated during shale gas drilling activities and pose potential risks to the environment, drawing increasing public and scientific attention. In this study, soil, wastewater and effluent samples were collected across multiple operational stages of shale gas development in Southwest China. A combination of in-situ gamma absorbed dose rate in air, soil radon concentration, radionuclide activity concentrations, and conventional hazard indices was used to evaluate environmental radioactivity and potential occupational exposure.
View Article and Find Full Text PDFAdv Mater
September 2025
Department of Mechanical Engineering, University of Alberta, Edmonton, AB, T6G 1H9, Canada.
Polyesters, with their tunable chemical structures and environmental sustainability, have drawn growing attention as solid polymer electrolytes for next-generation solid-state lithium metal batteries (SSLMBs). Through a comprehensive experimental and theoretical study involving the systematic variation of carbon chain lengths in the flexible (diol) and coordinating (diacid) segments, along with selective fluorination at distinct positions along the polymer backbone, 18 types of polyester are fabricated and demonstrate that fluorination at the coordinating segment significantly enhances ionic conductivity by suppressing crystallinity. In contrast, fluorination at the flexible segment reduces ionic migration barriers by providing more homogeneous coordinating sites, thereby improving the lithium-ion transference number, despite increasing chain rigidity and a reduction in overall ionic conductivity.
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