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NaSO oxidation reclaims 98.08% Li from spent LiFePO, while residual Fe-P components are reconstituted into NaFe(PO)PO/C Na-insertion and carbon coating. The regenerated cathode delivers 99.74% capacity retention (400 cycles, 1C) and 97.23% retention after 600 cycles (5C), demonstrating superior cyclability for sustainable battery recycling and low-cost energy storage.
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http://dx.doi.org/10.1039/d5cc02521d | DOI Listing |
Phys Chem Chem Phys
September 2025
Computational Inorganic Chemistry Group, Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy, Telangana 502284, India.
Over the past few years, alkali and alkaline earth metals have emerged as alternative catalysts to transition metal organometallics to catalyze the hydroboration of unsaturated compounds. A highly selective and cost-effective lithium-catalyzed method for the synthesis of an organoborane has been established based on the addition of a B-H bond to an unsaturated bond (polarized or unpolarized) using pinacolborane (HBPin). In the present work, the neosilyllithium-catalyzed hydroboration of nitriles, aldehydes, and esters has been investigated using high-level DLPNO-CCSD(T) calculations to unravel the mechanistic pathways and substrate-dependent reactivity.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China.
High entropy electrolytes show great potential in the design of next generation batteries. Demonstrating how salt components of high entropy electrolytes influence the charge storage performance of batteries is essential in the tuning and design of such advanced electrolytes. This study investigates the transport and interfacial properties for lithium hexafluorophosphate (LiPF) in ethylene carbonate and dimethyl carbonate (EC/DMC) solvent with commonly used additives for high entropy electrolytes (LiTFSI, LiDFOB, and LiNO).
View Article and Find Full Text PDFInt J Dent
August 2025
Department of Prosthodontics, The University of Iowa College of Dentistry and Dental Clinics, Iowa City 52242, Iowa, USA.
This study investigates light transmission through five types of computer-aided design/computer-aided manufacturing (CAD/CAM) lithium disilicate ceramics, varying in thickness (0.50, 1.00, and 1.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Department of Chemistry Education and Graduate Department of Chemical Materials, Pusan National University, Busan 46241, Republic of Korea.
Alkali salt-doped ionic liquids are emerging as promising electrolyte systems for energy applications, owing to their excellent interfacial stability. To address their limited ionic conductivity, various strategies have been proposed, including modifying the ion solvation environment and enhancing the transport of selected ions (e.g.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology, State Key Laboratory of Electrical Insulation and Power Equipment, Engineering Resea
Lithium metal batteries (LMBs) offer exceptional energy density and output voltage. However, their practical application remains hindered by sluggish ion transport and uncontrolled lithium dendrite formation, particularly under fast-charging conditions. Here, we report a facet-engineered anion-regulating separator based on zeolitic imidazolate framework-8 (ZIF-8) with preferentially crystal-exposed (110) facets.
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