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Traditional body-centered cubic (BCC) lattice metamaterials exhibit structural deficiencies including geometric discontinuity at cell connections and pronounced stress concentration at nodal regions, which restrict further enhancement of mechanical performance. This study proposes a novel lattice design methodology utilizing trigonometric function-modulated strut axes, yielding three novel trigonometric function curved rod cell-based lattice structures (TCRC, SCRC, and CCRC). By integrating fillet transition technology to achieve stress redistribution optimization, these configurations were systematically upgraded to TCRC-ipv, SCRC-ipv, and CCRC-ipv variants with enhanced structural performance. Experimental specimens were fabricated using selective laser melting (SLM) additive manufacturing technique, and the static mechanical response mechanisms were systematically investigated through quasi-static compression tests coupled with nonlinear finite element method (FEM) simulations. Results demonstrate that the trigonometric function-based topology optimization strategy combined with nodal fillet design significantly enhances overall structural performance. The TCRC-ipv configuration exhibits optimal comprehensive mechanical properties: compared with the reference BCC structure, it achieves 39.2% enhancement in elastic modulus, 59.4% increase in peak compressive strength, and 46.1% improvement in yield strength. Additionally, the energy absorption stress plateau elevates by 10.3%, with specific energy absorption capacity remarkably augmented by 86.1%. The proposed multiscale collaborative optimization strategy establishes a new theoretical framework and technical pathway for topology optimization design of lattice metamaterials in engineering applications.
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http://dx.doi.org/10.1038/s41598-025-06369-z | DOI Listing |
J Phys Chem Lett
September 2025
Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States.
Carbon dots (CDs) represent a new class of nontoxic and sustainable nanomaterials with increasing applications. Among them, bright and large Stokes-shift CDs are highly desirable for display and imaging, yet the emission mechanisms remain unclear. We obtained structural signatures for the recently engineered green and red CDs by ground-state femtosecond stimulated Raman spectroscopy (FSRS), then synthesized orange CDs with similar size but much higher nitrogen dopants than red CDs.
View Article and Find Full Text PDFJ Synchrotron Radiat
November 2025
State Key Laboratory of Chemical Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People's Republic of China.
This study develops an integrated X-ray absorption spectroscopy (XAS) photoemission electron microscopy (PEEM) platform on beamline BL09U at the Shanghai Synchrotron Radiation Facility (SSRF), enabling nanoscale characterization of complex materials through energy-resolved imaging and local-area XAS. By using the wide range of energy tunability, full access to different polarizations and PEEM's surface sensitivity, we have established a gap-monochromator control system under the EPICS framework to synchronize the elliptically polarized undulator (EPU) gap and monochromator energy dynamically, optimizing photon flux stability for absorption fine structure analysis. Combining X-ray magnetic circular dichroism (XMCD) and X-ray magnetic linear dichroism (XMLD) with PEEM and local-area XAS, this platform achieves concurrent mapping of electronic structures and magnetic domains in ferromagnetic nano-patterns, as demonstrated through our studies of NiFe Permalloy using this system.
View Article and Find Full Text PDFJ Fluoresc
September 2025
Chemical Engineering Department, College of Engineering, University of Ha'il, P.O. Box 2440, 81441, Ha'il, Saudi Arabia.
This review delivers a focused and critical evaluation of recent progress in the green synthesis of carbon quantum dots (CQDs), with particular attention to state-of-the-art approaches utilizing renewable biomass as precursors. The main objective is to systematically examine innovative, environmentally friendly methods and clarify their direct influence on the core properties and photocatalytic performance of CQDs. The novelty of this review stems from its comprehensive comparison of green synthetic pathways, revealing how specific processes determine key structural, optical, and electronic attributes of the resulting CQDs.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Shock Wave Research Laboratory, Department of Physics, Abdul Kalam Research Center, Sacred Heart College (Autonomous), affiliated to Thiruvalluvar University, Tirupattur, Tamil Nadu, 635 601, India.
Bismuth ferrite (BiFeO) is a semiconductor with multiferroic properties, synthesized by the sol-gel method. While static high-pressure studies have advanced our understanding of the phase behavior of BiFeO, the effects of dynamic pressure acoustic shock waves remain unexplored. In this study, BiFeO was subjected to 100 shock pulses with 0.
View Article and Find Full Text PDFSmall
September 2025
College of Science, Nanjing Forestry University, Nanjing, 210037, China.
Inspired by the rigid exoskeleton and elastic inner tissues of crustaceans, a bilayer gel integrating high-strength rigidity and soft cushioning with high interfacial adhesion (1060 ± 40 J m ) is developed via a stepwise solid-liquid phase crosslinking strategy. Herein, a prefrozen high-concentration polyvinyl alcohol (PVA) solution forms a solid-state structural framework, while a subsequently cast low-concentration PVA solution generates a flexible layer. Partial thawing of the frozen gel during casting triggers molecular chain interpenetration at the interface, synergistically enhanced by controlled molecular penetration, freeze-thaw cycles, and salt-induced crystallization.
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