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Infrared windows-enabled infrared inspection has significant applications in both civilian and military domains. However, the static and indiscriminate transparency across the visible to infrared regions renders them vulnerable to potential laser damage. In this study, we construct a dynamic infrared optical switch based on a vanadium dioxide (VO)-Al metasurface structure. The phase transition of VO enables dynamic transmittance switching, while the Al metasurface confines this capability to specific wavelengths to mitigate unwanted interferences. The infrared switch transmits light within the 8-14 μm range only in its "ON" state, reflecting other wavelengths across the visible to infrared spectrum. The underlying physics is attributed to plasmon-induced extraordinary optical transmission combined with the reconfigurable metatronic properties of the VO layer. Moreover, while maintaining excellent optical performance, we utilize full-wave simulations to enlarge the feature sizes of the Al metasurface structure to meet the demands for large-area fabrication. This advancement paves the way for practical applications of infrared switches, highlighting significant research implications for intelligent infrared windows and enhancing our understanding of light-matter interactions in reconfigurable photothermal devices.
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http://dx.doi.org/10.1515/nanoph-2025-0074 | DOI Listing |
Org Lett
September 2025
Department of Chemistry, Indian Institute of Techology Bombay, Powai, Mumbai 400076, India.
The direct α-α coupling of 3-pyrrolyl boron dipyrromethenes (BODIPYs) affords helical near-infrared (NIR)-active dimers in one step via a radical Pd-catalyzed process. X-ray analysis reveals Z-type helical packing stabilized by π-π stacking and hydrogen-bonding interactions. These dimers showed pronounced bathochromic absorption shifts compared to monomers and solvent-dependent charge-transfer bands up to 905 nm with fluorescence quenching.
View Article and Find Full Text PDFChemistry
September 2025
Department of Chemistry, Birla Institute of Technology and Science-Pilani, K K Birla Goa Campus, Zuarinagar, Goa, 403726, India.
This study investigates the unique syneresis (self-shrinking) behavior of N-Terminally Fmoc-protected amino acid, Fmoc-hPhe-OH (Fmoc-homo-L-phenylalanine, abbreviated in this work as hF)-based hydrogel, and its potential in environmental remediation applications. Fmoc-hPhe-OH (hF) forms a hydrogel in 50 mM phosphate buffer (PB) of pH 7.4.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Chemical Engineering, Keimyung University, Daegu 42601, Republic of Korea.
Indium tin oxide (Sn/InO) is a degenerately doped semiconductor nanocrystal (NC) that exhibits localized surface plasmon resonance (LSPR) in the short-wavelength infrared electromagnetic spectral range. Alternative to metals, the tunability of LSPR is possible in doped semiconductor NCs by controlling the dopant type, doping level, and opto-electrochemical modulation. In this study, dopant oxidation valency in carrier density and LSPR peaks (Sn(IV): 1.
View Article and Find Full Text PDFStem Cell Rev Rep
September 2025
Paris Cité University, INSERM UMR-S 970, Paris Cardiovascular Research Centre, Paris, France.
Endothelial Colony-Forming Cells (ECFCs) are recognized as key vasculogenic progenitors in humans and serve as valuable liquid biopsies for diagnosing and studying vascular disorders. In a groundbreaking study, Anceschi et al. present a novel, integrative strategy that combines ECFCs loaded with gold nanorods (AuNRs) to enhance tumor radiosensitization through localized hyperthermia.
View Article and Find Full Text PDFObes Surg
September 2025
Department of Experimental Vascular Medicine, Amsterdam University Medical Centers, Amsterdam, Netherlands.
Background: Roux-en-Y gastric bypass (RYGB) and sleeve gastrectomy (SG) are common bariatric procedures that lead to substantial and sustained weight loss. Although both procedures induce hormonal and physiological effects, RYGB includes both a restrictive and malabsorptive component due to anatomical rerouting, whereas SG is considered primarily restrictive. This study aimed to quantify differences in energy and fat absorption between both procedures using near-infrared spectroscopy (NIRS).
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