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Quantum states encoded in the time-bin degree of freedom of photons represent a fundamental resource for quantum information protocols. Traditional methods for generating and measuring time-bin-encoded quantum states face severe challenges due to optical instabilities, complex setups, and timing resolution requirements. To circumvent these issues, we leverage an approach based on Hong-Ou-Mandel interference and we propose and demonstrate a robust and scalable protocol to generate and measure arbitrary high-dimensional time-bin quantum states. We experimentally implement the protocol in a photonic setup reaching high-fidelity quantum state tomographies of two- and three-dimensional quantum states encoded in time bins with short temporal separation. We also certify intrasystem polarization-time entanglement of single photons through a nonclassicality test. The demonstrated approach enables access to high-dimensional states and tasks that are practically inaccessible with standard schemes, thereby advancing fundamental quantum information science and opening applications in quantum communication.
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http://dx.doi.org/10.1103/PhysRevLett.134.180802 | DOI Listing |
J Am Chem Soc
September 2025
Division of Chemistry and Chemical Engineering, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125, United States.
Coherent electron spin states within paramagnetic molecules hold significant potential for microscopic quantum sensing. However, all-optical coherence measurements amenable to high spatial and temporal resolution under ambient conditions remain a significant challenge. Here we conduct room-temperature, picosecond time-resolved Faraday ellipticity/rotation (TRFE/R) measurements of the electron spin decoherence time in [IrBr].
View Article and Find Full Text PDFJ Fluoresc
September 2025
Chemical Engineering Department, College of Engineering, University of Ha'il, P.O. Box 2440, 81441, Ha'il, Saudi Arabia.
This review delivers a focused and critical evaluation of recent progress in the green synthesis of carbon quantum dots (CQDs), with particular attention to state-of-the-art approaches utilizing renewable biomass as precursors. The main objective is to systematically examine innovative, environmentally friendly methods and clarify their direct influence on the core properties and photocatalytic performance of CQDs. The novelty of this review stems from its comprehensive comparison of green synthetic pathways, revealing how specific processes determine key structural, optical, and electronic attributes of the resulting CQDs.
View Article and Find Full Text PDFLangmuir
September 2025
Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19104, United States.
The surfaces of 1D layered lepidocrocite-structured titanates (1DLs) are negatively charged due to an oxygen-to-titanium atomic ratio >2. This, and their layered structure, allow for facile ion exchange and high colloidal stability, demonstrated by ζ-potentials of ≈ -85 mV at their unadjusted pH of ≈10.4.
View Article and Find Full Text PDFJ Chem Theory Comput
September 2025
State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials Oriented Chemical Engineering, Department of Pharmaceutical Sciences, Institute of Chemical Process Systems Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China.
Organometallic catalysis lies at the heart of numerous industrial processes that produce bulk and fine chemicals. The search for transition states and screening for organic ligands are vital in designing highly active organometallic catalysts with efficient reaction kinetics. However, identifying accurate transition states necessitates computationally intensive quantum chemistry calculations.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87106, United States.
Defects significantly influence charge transport in CHNHPbI (MAPbI) perovskite solar cells, particularly at interfaces. Using quantum dynamics simulation, we reveal a distinct interstitial iodine (I) defect behavior at different positions in the TiO/MAPbI system. In the perovskite bulk-like region, I exhibits high mobility and dissociates detrimental iodine trimers, facilitating small-to-large polaron transition and promoting shallow trap formation.
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