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Article Abstract
We describe the precise nano-assembly of an antenna-single-atom-reactor based on a UiO-66-(SH) metal-organic framework support. We lock Ag plasmon nanoparticles in the thio-functionalized pore channels Ag-S interaction, and anchor Cu single atoms on the oxygen-bridged Zr cluster anodes based on Cu-O bonds, leading to highly dispersed AgCu@UiOS with exceptional catalytic activity for the photocatalytic reduction of CO.
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