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Objective: This study enhanced wood-activated carbon using ammonia chemical vapor deposition (NH-CVD) to improve its adsorption properties for carbamazepine (CBZ).
Methods: Modification was done in a vacuum tube sintering furnace. We used X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) method, and Fourier Transform Infrared Spectroscopy (FTIR) for characterization and analysis. Kinetic adsorption and isothermal adsorption tests were carried out by UV spectrophotometry.
Results: NH-CVD significantly increased the micropore volume and surface area, notably in the sample, and raised the nitrogen content on the carbon surface. The adsorption capacity of modified activated carbon () reached 130.81 mg/g, outperforming the unmodified () at 72.46 mg/g. FTIR results indicated strong hydrogen bonding with CBZ molecules.
Conclusion: NH-CVD modification improves CBZ adsorption on wood activated carbon by increasing micropore volume and enhancing hydrogen bonding, confirming a single-layer adsorption on a heterogeneous surface.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11923042 | PMC |
http://dx.doi.org/10.2147/IJN.S495746 | DOI Listing |
J Environ Manage
September 2025
National and Local Joint Engineering Laboratory of Municipal Sewage Resource Utilization Technology, Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment, School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou, 215009, Ch
The anaerobic ammonia oxidation (anammox) process has attracted considerable interest for its advantages in low energy requirements, reduced sludge output, and eliminating the need for external carbon sources. However, its application is constrained by the long generation time, slow growth, and challenges in enriching anammox bacteria. Studies indicate that carbon material addition significantly accelerates anammox bacteria proliferation, enhances nitrogen removal efficiency, and improves anammox microbial activity.
View Article and Find Full Text PDFJ Contam Hydrol
September 2025
School of Life Sciences, Qufu Normal University, Qufu 273165, PR China.
Biological denitrification is an essential method for sewage treatment, though its efficiency is often constrained by low temperatures and insufficient organic carbon sources. In this study, a novel cold-tolerant heterotrophic nitrification-aerobic denitrification bacterium, Pseudomonas fluorescens sp. Z03, was isolated from activated sludge, and its denitrification performance was evaluated.
View Article and Find Full Text PDFRSC Adv
September 2025
Department of Chemical Engineering and Green Technology, Institute of Chemical Technology (ICT) Mumbai Maharashtra 400019 India
The sustainable synthesis of bio-based monomers from renewable biomass intermediates is a central goal in green chemistry and biorefinery innovation. This study introduces a synergistic catalytic-enzymatic strategy for the efficient and eco-friendly oxidation of 5-hydroxymethylfurfural (5-HMF) into 2,5-furandicarboxylic acid (FDCA), a key monomer for next-generation biodegradable plastics. The catalytic phase employed non-noble metal catalysts, MnO and Co-Mn supported on activated carbon (Co-Mn/AC), under mild batch reaction conditions at 90 °C.
View Article and Find Full Text PDFNatl Sci Rev
September 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China.
Chimeric antigen receptor T (CAR-T)-cell therapy is a promising resolution for solid tumors, but its corresponding clinical translation has been hindered by unsatisfactory therapeutic potency and severe cytokine release syndrome. Herein, tetracycline (Tet)-On inducible human epidermal growth factor receptor 1 (HER1)-targeted CAR-T (Tet-HER1-CAR-T) cells were engineered to enable spatially selective activation at tumor sites by doxycycline (Doxy), which is delivered by pH-responsive stealth liposomal calcium carbonate nanoparticles (Doxy@CaCO-PEG). Compared with the intravenous administration of conventional HER1-CAR-T cells and Tet-HER1-CAR-T cells activated by free Doxy, concurrent intravenous administration of Tet-HER1-CAR-T cells and Doxy@CaCO-PEG leads to the localized tumor activation of Tet-HER1-CAR-T cells and reduced systemic secretion of inflammatory cytokines.
View Article and Find Full Text PDFEnviron Monit Assess
September 2025
School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300, Nibong Tebal, Penang, Malaysia.
Ciprofloxacin (CIP), a widely used fluoroquinolone antibiotic, has become a significant contaminant in aquatic environments due to its extensive use and incomplete metabolism. This review comprehensively analyses CIP pollution, including its sources, environmental and health impacts, and removal strategies. Chemical methods such as advanced oxidation processes and physical techniques like adsorption are evaluated for their efficiency in CIP removal.
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