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An important route of engineering topological states and excitations is to combine superconductors (SC) with the quantum Hall (QH) effect, and over the past decade, significant progress has been made in this direction. While typical measurements of these states focus on electronic properties, little attention has been paid to the accompanying thermal responses. Here, we examine the thermal properties of the interface between type-II superconducting electrodes and graphene in the QH regime. We use the thermal noise measurement to probe the local electron temperature of the superconductor next to the biased interface. Surprisingly, the measured temperature rise indicates that the superconductor provides a significant thermal conductivity, which is linear in temperature. This suggests electronic heat transport and may be unexpected, because the number of the quasiparticles in the superconductor should be exponentially suppressed. Instead, we attribute the measured electronic heat conductivity to the overlap of the normal states in the vortex cores.
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http://dx.doi.org/10.1103/PhysRevLett.134.066001 | DOI Listing |
Luminescence
September 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, Beijing, China.
A novel aggregation-induced emission (AIE) system with superior performance was successfully developed through local chemical modification from thiophene to thiophene sulfone. This approach, leveraging easily accessible tetraphenylthiophene precursors, dramatically enhances the photophysical properties in a simple oxidation step. Notably, the representative 2,3,4,5-tetraphenylthiophene sulfone (3c) demonstrates remarkable solid-state emission characteristics with a fluorescence quantum yield of 72% and an AIE factor of 240, substantially outperforming its thiophene analog.
View Article and Find Full Text PDFJ Biomater Sci Polym Ed
September 2025
North Eastern Federal University, Yakutsk, Russia.
The survey assessed tribological properties of the materials based on ultra-high-molecular-weight polyethylene for joint replacement liners by several major manufacturers. Being their crucial parameter, the mass wear rates were compared. Scanning electron microscopy was used to assess the metamorphosis of the materials surface after friction.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China.
Developing solid electrolytes with high ionic conductivity, a high voltage window, low flammability, and excellent interface compatibilities with both the anode and cathode for lithium-metal batteries is still a great challenge but highly desirable. Herein, we achieve this target through an in situ copolymerization of vinyl ethylene carbonate (VEC) together with acrylonitrile (AN) under fitting ratios inside a porous polyacrylonitrile (PAN) fiber membrane doped with flame-retardant decabromodiphenyl ethane (DBDPE) molecules. The received fiber-reinforced polycarbonate-based composite electrolyte with an ultrathin thickness of 13 μm exhibits good internal interfacial compatibility because of the same AN structure and superior flame-retardant performance due to the doped DBDPE molecules.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an, 710129, P.R. China.
MXenes serve as pivotal candidates for pseudocapacitive energy storage owing to sound proton/electron-transport capability and tunable topology. However, the metastable surface terminal properties and the progressive oxidation leads to drastic capacity fading, posing significant challenges for sustainable energy applications. Here, with the aramid nanofiber as the interface mediator, we engineer the thermal reconstruction of MXenes to synergistically introduce interfacial covalent and noncovalent interactions, resulting in a high specific capacitance of 531.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Institute of Pharmaceutical Science, King's College London, Franklin Wilkins Building, Stamford Street, London, SE1 9NH, UK.
As supramolecular assemblies, polypseudorotaxanes (PPR) exhibit inherent advantages in modular adaptability and structural programmability, with the potential to build tuneable platforms integrating various functionalities. Here we report the "one-pot" preparation of a self-assembled thiol-rich PPR (SPPR), where thiolated-α-cyclodextrins (SHαCD) spontaneously thread onto polymers, and are then crosslinked into a three-dimensional network by the thermally-triggered oxidation of thiols into disulfide bonds. The dynamic thiol groups along the SPPR provide remarkable modularity for the functionalization of thiophilic metal nanoparticles (NPs), exemplified by two application vectors.
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