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2D photothermal membranes have demonstrated numerous advantages in solar desalination due to their flexibility, scalability, and low cost. However, their practical applications are limited by the restricted evaporation area and obstructed vapor channels. A biomimetic design of the breathable 2D photothermal fabric is reported, which is composed of two carbon-nanotube-hydrogel-coated polyester (PET) fabrics separated by fiber pillars, with the upper fabric layer having a hole array as stomatal channels. This fabric shows high solar-absorption efficiency (96.1%) and decreased water-evaporation enthalpy (1664.6 kJ kg). The hanging fabric as a heliotropic evaporator exhibits four-plane evaporation feature and achieves a high evaporation rate of 2.6 kg m h under sunlight (1.0 kW m) illumination, better than the traditional floated model (single-plane, 1.6 kg m h). The evaporation rate can be further enhanced to 4.2 kg m h upon introducing adscititious airflow (2 m s). Simultaneously, the heliotropic-hanging design allows the dropping of concentrated brine, avoiding solid-salt-crystallization.
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http://dx.doi.org/10.1002/adma.202420482 | DOI Listing |
Small
September 2025
College of Science, Nanjing Forestry University, Nanjing, 210037, China.
Inspired by the rigid exoskeleton and elastic inner tissues of crustaceans, a bilayer gel integrating high-strength rigidity and soft cushioning with high interfacial adhesion (1060 ± 40 J m ) is developed via a stepwise solid-liquid phase crosslinking strategy. Herein, a prefrozen high-concentration polyvinyl alcohol (PVA) solution forms a solid-state structural framework, while a subsequently cast low-concentration PVA solution generates a flexible layer. Partial thawing of the frozen gel during casting triggers molecular chain interpenetration at the interface, synergistically enhanced by controlled molecular penetration, freeze-thaw cycles, and salt-induced crystallization.
View Article and Find Full Text PDFRegen Biomater
August 2025
Institute of Stomatology & Oral Maxilla Facial Key Laboratory, First Medical Center of Chinese PLA General Hospital, Beijing 100853, China.
Reconstructing bone defects remains a significant challenge in clinical practice, driving the urgent need for advanced artificial grafts that simultaneously promote vascularization and osteogenesis. Addressing the critical trade-off between achieving high porosity/strength and effective bioactivity at safe ion doses, we incorporated strontium (Sr) into β-tricalcium phosphate (β-TCP) scaffolds with a triply periodic minimal surface (TPMS) structure using digital light processing (DLP)-based three-dimensional (3D) printing. Systematically screening Sr concentrations (0-10 mol%), we identified 10 mol% as optimal, leveraging the synergy between the biomimetic TPMS architecture, providing exceptional mechanical strength (up to 1.
View Article and Find Full Text PDFMater Today Bio
October 2025
Department of Vascular Surgery, The Affiliated Hospital of Southwest Medical University, 646000, Luzhou, China.
Atherosclerosis (AS) is a chronic inflammatory disease driven by endothelial dysfunction, vascular smooth muscle cell proliferation, and insufficient resolution of inflammation. Nitric oxide (NO) plays a crucial role in vascular homeostasis by promoting endothelial cell proliferation, maintaining endothelial integrity, suppressing smooth muscle cell hyperplasia, and exerting potent anti-inflammatory effects. However, clinical application of NO is hindered by its short half-life, lack of targeting, and uncontrolled release.
View Article and Find Full Text PDFDalton Trans
September 2025
Department of Chemistry, Indian Institute of Technology Guwahati, Assam 781039, India.
Motivated by copper's essential role in biology and its wide range of applications in catalytic and synthetic chemistry, this work aims to understand the effect of heteroatom substitution on the overall stability and reactivity of biomimetic Cu(II)-alkylperoxo complexes. In particular, we designed a series of tetracoordinated ligand frameworks based on iso-BPMEN = (,-bis(2-pyridylmethyl)-','-dimethylethane-1,2-diamine) with varying the primary coordination sphere using different donor atoms (N, O, or S) bound to Cu(II). The copper(II) complexes bearing iso-BPMEN and their modified heteroatom-substituted ligands were synthesized and structurally characterized.
View Article and Find Full Text PDFAdv Healthc Mater
September 2025
National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China.
Melasma is a facial hyperpigmentation disease that significantly impacts patients' quality of life. Clinical treatment is limited by the short half-lives and hydrophilicity of drugs, necessitating release curve optimization to maintain a stable therapeutic concentration for an extended period. This article utilizes natural biomaterials to design a core-shell structured microneedle, combining the "immediate release" and "delayed release" module to achieve programmed drug release.
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