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Article Abstract
We report a -quinodimethane skeleton (-QDM)-based polycyclic aromatic hydrocarbon (PAH) with heptenes as end-capping groups and F-substituents in the central six-membered ring. This compound shows the -configuration in one crystal form with relative strong emission ( = 0.25), and the -configuration in another crystal form with weak emission. Furthermore, this compound was transformed into the more annulated PAHs on-surface C-F bond activations.
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