Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
In this study, we synthesized CeO possessing an open pore structure and verified its structural differences compared to CeO lacking such an open pore structure. Using these two CeO samples as catalyst supports and loading them with Pd metals, a series of characterizations were carried out on the resultant catalysts to analyze their structures and properties meticulously. We have elucidated the influence of the open pore structure on the loading position of Pd. Hydrogenation reactions involving alkynes and alkenes were employed to confirm the existence of steric hindrance effects caused by the pore structure differences. Furthermore, we applied these catalysts to more valuable industrial reaction systems, demonstrating that the unique pore structures of directly synthesized CeO can also exhibit excellent performance in practical applications.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acsami.4c19940 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Structural Basis for HIV-1 Maturation Inhibition by PF-46396 Determined by MAS NMR.
J Am Chem Soc
September 2025
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
Among the different types of HIV-1 maturation inhibitors, those that stabilize the junction between the capsid protein C-terminal domain (CA) and the spacer peptide 1 (SP1) within the immature Gag lattice are promising candidates for antiretroviral therapies. Here, we report the atomic-resolution structure of CA-SP1 assemblies with the small-molecule maturation inhibitor PF-46396 and the assembly cofactor inositol hexakisphosphate (IP6), determined by magic angle spinning (MAS) NMR spectroscopy. Our results reveal that although the two PF-46396 enantiomers exhibit distinct binding modes, they both possess similar anti-HIV potency.
View Article and Find Full Text PDFA new true triaxial apparatus with pore fluid system for rock deformation under representative crustal stress conditions.
Rev Sci Instrum
September 2025
Department of Earth Sciences, University College London, London, United Kingdom.
We have developed a new true triaxial apparatus for rock deformation, featuring six servo-controlled loading rams capable of applying maximum stresses of 220 MPa along the two horizontal axes and 400 MPa along the vertical axis to cubic rock samples of 50 mm side. Samples are introduced into a steel vessel, allowing rock specimens to be subjected to confining pressures of up to 60 MPa. Pore fluid lines connected to two pump intensifiers enable high-precision permeability measurements along all three principal stress directions.
View Article and Find Full Text PDFEffect of Clays on the Spontaneous Imbibition Behavior of Surfactant Solutions in Shale Oil Reservoirs.
Langmuir
September 2025
Key Laboratory of Unconventional Oil & Gas Development (China University of Petroleum (East China)), Ministry of Education, Qingdao 266580, China.
Surfactant-enhanced spontaneous imbibition is a proven method of enhancing oil recovery from shale reservoirs. However, a significant knowledge gap concerning the impact of clay minerals on surfactant-enhanced imbibition in shale reservoirs remains. Therefore, this study first analyzed the mineral composition and pore structure of the shale reservoirs.
View Article and Find Full Text PDFSynergistic Ni-Co Metal Nodes in a Conjugated MOF-Modified Separator for High-Performance Lithium-Sulfur Batteries.
Adv Sci (Weinh)
September 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
Lithium-sulfur batteries (LSBs) hold great potential as next-generation energy storage systems due to their high theoretical energy density and relatively low cost. However, their practical application is hindered by issues such as the shuttle phenomenon caused by soluble lithium polysulfides (LiPSs), slow redox reaction rates, and unsatisfactory cycling stability. In this study, novel conjugated metal-organic frameworks, MM″(HHTP) (M, M″ = Ni, Co, Cu) is reported, as a functional coating on polypropylene (PP) separators.
View Article and Find Full Text PDFAdditive Manufactured Programmable Scaffold Sensor Based on Triply Periodic Minimal Surfaces for Broad-Spectrum Pressure Detection.
ACS Appl Mater Interfaces
September 2025
DUT School of Software Technology & DUT-RU International School of Information Science and Engineering, Dalian University of Technology, Dalian 116620, China.
Achieving both high sensitivity and a wide detection range in flexible pressure sensors poses a challenge due to their inherent trade-off. Although porous structures offer promising solutions, conventional methods (templating, foaming, and freeze-drying) fail to precisely control cavity dimensions, spatial arrangement, and 3D morphology, which are crucial for sensing performance. Here, we propose a scalable fabrication strategy that integrates triply periodic minimal surface (TPMS) geometries─precisely engineered via FDM 3D printing─with ultrasonic impregnation of carbon black (CB) into TPU scaffolds.
View Article and Find Full Text PDF