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The low laser-induced damage threshold (LIDT) of HfO/SiO films is an important factor in limiting the further development of high repetition rate femtosecond (fs) laser systems. Conventional whole-layer annealing can effectively improve the properties of SiO films, but it is difficult to improve the properties of HfO films located in the intermediate layer and is also prone to introduce contaminants. In this study, an innovative magnetron sputtering-vacuum tube furnace combined system was presented to deposit and anneal the HfO/SiO films without contaminant. The layer-by-layer annealing optimizes the stoichiometric ratio, stress, and surface morphology of HfO/SiO films. The fs laser damage test at a high repetition rate indicated that the LIDT of the layer-by-layer annealed films reached 1.15 J/cm and 1.99 J/cm at 515 nm and 1030 nm, which were about 28% and 25% higher than those of the un-annealed films, respectively. This work provides a way to effectively avoid the contaminant introduction during annealing and improve the damage threshold of bilayer films by layer-by-layer annealing in the magnetron sputtering-vacuum tube furnace combined system.
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http://dx.doi.org/10.1364/OE.529303 | DOI Listing |
Nat Commun
July 2025
State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (NanjingTech), Nanjing, Jiangsu, China.
Thermal-evaporated perovskite light-emitting diodes are highly promising for future display and lighting. However, multi-source co-evaporation faces challenges such as difficulty in regulating crystallinity, especially for red perovskite light-emitting diodes, whose external quantum efficiencies are still less than 2%. Here, we demonstrate a facile layer-by-layer thermal-evaporation strategy to fabricate high-quality perovskite-emitting films with tunable emission wavelengths.
View Article and Find Full Text PDFSoft Matter
July 2025
Department of Materials Science & Engineering, Texas A&M University, College Station, Texas 77843, USA.
The layer-by-layer deposition of polyelectrolyte multilayers (PEMs) is a versatile and widely used technique of forming nanoscale polymer films with controlled properties. Yet, the influence of polymer architecture and assembly conditions on the mechanical properties of PEM films is not well understood. In this paper, we compare the growth and mechanical properties of all-linear PEM films all-star (8-arm) PEM films assembled at varied assembly pH.
View Article and Find Full Text PDFAdv Mater
March 2025
Laboratoire Albert Fert, CNRS, Thales, Université Paris Saclay, 91767, Palaiseau, France.
Layered perovskite-based compounds offer a range of unconventional properties enabled by their naturally anisotropic structure. Among these, the Carpy-Galy phases (ABO), characterized by (110)-oriented perovskite planes interleaved with additional oxygen layers, stand out for robust in-plane polarization. However, the challenges associated with the synthesis of ultrathin Carpy-Galy films and understanding the impact of strain on their properties limit their integration into devices.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Institute for Technical Chemistry, Braunschweig University of Technology, 38106 Braunschweig, Germany.
Tissue engineering has emerged as a promising approach for improved regeneration of native tissue and could increase the quality of life of many patients. However, the treatment of injured tissue transitions is still in its early stages, relying primarily on a purely physical approach in medical surgery. A biodegradable implant with a modified surface that is capable of biological active protein delivery via a nanoparticulate release system could advance the field of musculoskeletal disorder treatments enormously.
View Article and Find Full Text PDFAdv Mater
March 2025
Department of Materials Science and Engineering, University of Pennsylvania, 3231 Walnut Street, Philadelphia, PA, 19104, USA.
Cholesteric liquid crystal elastomers (CLCEs) hold great promise for mechanochromic applications in anti-counterfeiting, smart textiles, and soft robotics, thanks to the structural color and elasticity. While CLCEs are printed via direct ink writing (DIW) to fabricate free-standing films, complex 3D structures are not fabricated due to the opposing rheological properties necessary for cholesteric alignment and multilayer stacking. Here, 3D CLCE structures are realized by utilizing coaxial DIW to print a CLC ink within a silicone ink.
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