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Aromatic chlorinated compounds and Cr(VI) in groundwater pose significant challenges due to their resistance. This study explores microbial fuel cells using low-cost Si-modified ferrihydrite (SiFh) electrodes for simultaneous chlorobenzene and Cr(VI) removal. The voltage output of MFC assembled with SiFh modified electrode was approximately 1.63 times higher than the bare electrode, achieving 1.23 times higher in chlorobenzene degradation efficiency. CF-SiFh loaded MFC had the highest power generation and best EET efficiency, which was positive to greatest and fastest chlorobenzene removal. Microbial community analysis identified the dominance of Cupriavidus and Pandoraea in chlorobenzene oxidation, while Lentimicrobiaceae and Rhodobacteraceae were key genera that may facilitate direct and indirect electron transfer within the biofilms. Cr species analysis in solution and solids confirmed it was reduced to Cr(OH) or CrFe(OH) coprecipitates at cathode. MFCs with SiFh-modified electrodes thus offer a promising technology for simultaneous chlorinated compound and Cr(VI) removal, promising in contaminated groundwater remediation.
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http://dx.doi.org/10.1016/j.biortech.2024.131639 | DOI Listing |
Bioresour Technol
December 2024
Department of Environmental Science and Engineering, Fudan University, Shanghai 200438, China. Electronic address:
Aromatic chlorinated compounds and Cr(VI) in groundwater pose significant challenges due to their resistance. This study explores microbial fuel cells using low-cost Si-modified ferrihydrite (SiFh) electrodes for simultaneous chlorobenzene and Cr(VI) removal. The voltage output of MFC assembled with SiFh modified electrode was approximately 1.
View Article and Find Full Text PDFJ Environ Manage
May 2024
Department of Environmental Science and Engineering, College of Architecture and Environment, Sichuan University, Chengdu, 610065, PR China.
Environ Res
January 2023
College of Environmental Science and Engineering, Guilin University of Technology, 319 Yanshan Street, Guilin, 541000, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Areas, Guilin University of Technology, 319 Yanshan Street, Guilin, 541000, Chin
The composite pollution by Cr(VI) and p-chlorophenol (4-CP) has high toxicity and harms water safety. However, research on the effective removal of Cr(VI) and 4-CP composite-polluted wastewater (C&P) and efficient synchronous electricity generation with reclaimed resources is limited. In this study, a downflow Leersia hexandra constructed wetland-microbial fuel cell (DLCW-MFC) was builded to treat C&P, as well as wastewater singularly polluted by Cr(VI) (SC) and 4-CP (SP), respectively, to reveal the mechanism by which DLCW-MFC treats C&P and synchronously generates electricity.
View Article and Find Full Text PDFEnviron Technol
January 2024
College of Environmental Science and Engineering, Guilin University of Technology, Guilin, People's Republic of China.
Cr(VI) and p-chlorophenol (4-CP) are common pollutants in the aquatic environment but are difficult to degrade and have complex toxic effects. A downflow microbial fuel cell (DLCW-MFC) system was constructed to purify Cr(VI) and 4-CP polluted wastewater, as well as to investigate the effects of different pHs on Cr(VI) and 4-CP removal, electrochemical performance, physiological and biochemical responses, and Cr enrichment status of . .
View Article and Find Full Text PDFJ Hazard Mater
September 2022
State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, China; College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China. Electronic address:
Catalytic hydrogenation can selectively destabilize and detoxify specific contaminants in water. Herein, to explore safer and more efficient hydrogen sources, hydrogen rich balls (HRBs) were researched and applied for hydrogenating p-chlorophenol and Cr(VI) over Pd/C catalyst. The results showed that HRBs can realize the sustained release of H by replacing the hydrogen in water, and generate the refined (micro/nano-sized) H bubble, which effectively improves the adsorption and activation effectively of H molecules on Pd/C catalyst, and the hydrogen atoms utilization efficiency during p-chlorophenol hydrodechlorination is as high as 3.
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