A Temperature-Sensitive Fluorescent Supramolecular Polymer Constructed by Discrete Platinum(II) Metallacycle and Pillar[5]arene-Based Host-Guest Interactions.

Inorg Chem

Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China.

Published: October 2024


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Article Abstract

The application of thermosensitive fluorescent supramolecular polymers in advanced optical materials, chemical sensors, artificial optical devices, and external stimulus responses remains underdeveloped. In this study, we introduced a novel method for constructing a mechanically interlocked fluorescent supramolecular polymer utilizing host-guest interactions, including C-H···π interactions and π-π stacking. This polymer exhibits outstanding temperature-sensitive fluorescence properties and is environmentally friendly due to its recyclability. Leveraging the polymer's fluorescence response at critical temperature ranges, we developed a high-temperature warning device. This device utilizes the temperature-sensitive fluorescence characteristic of the polymer to indicate dangerous temperature levels, thereby demonstrating its potential in practical safety applications.

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http://dx.doi.org/10.1021/acs.inorgchem.4c03727DOI Listing

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