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The present work envisages a chelation driven, facile, selective, and rapid method for uranium(VI) separation from a (U, Th) mixture using 1-hydroxy-2-pyridone (1,2-HOPO). Herein, U(VI) was selectively precipitated as the neutral [UO(HOPO)(HO)]·HO (orange colored) complex while Th(IV) and other metal ions remained in the solution. The pH of the medium played a key role in facilitating the separation process.
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http://dx.doi.org/10.1021/acs.inorgchem.4c01779 | DOI Listing |
RSC Adv
September 2025
Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC C/Sor Juana Inés de la Cruz, 3 Madrid 28049 Spain
Perovskite light-emitting diodes (PeLEDs) have emerged as a promising technology for next-generation display and lighting applications, thanks to their remarkable colour purity, tunability, and ease of fabrication. In this work, we explore the incorporation of plasmonic spherical nanoparticles (NPs) directly embedded into the green-emitting CsPbBr perovskite layer in a PeLED as a strategy to enhance both its optical and electrical properties. We find that plasmonic effects directly boost spontaneous emission while also influencing charge carrier recombination dynamics.
View Article and Find Full Text PDFJ Immunother Precis Oncol
August 2025
Department of Medical Oncology, Sir H N Reliance Foundation Hospital and Research Centre, Mumbai, India.
Pulmonary sarcomatoid carcinoma (PSC) is a rare and aggressive subtype of non-small cell lung cancer (NSCLC) with limited treatment options and poor prognosis. mutations generally respond to tyrosine kinase inhibitors (TKIs)-based targeted therapy but are typically associated with resistance to immunotherapy. We report a case of oligometastatic PSC harboring compound mutations (p.
View Article and Find Full Text PDFChem Sci
September 2025
School of Resources, Environment and Materials, Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, Guangxi University Nanning 530004 P. R. China
To overcome the persistent challenges of sluggish lithium polysulfide (LiPS) conversion kinetics and the shuttle effect in Li-S batteries, this work introduces a novel, cost-effective thermal treatment strategy for synthesizing high-entropy metal phosphide catalysts using cation-bonded phosphate resins. For the first time, we successfully fabricated single-phase high-entropy FeCoNiCuMnP nanoparticles anchored on a porous carbon network (HEP/C). HEP/C demonstrates enhanced electronic conductivity and superior LiPS adsorption capability, substantially accelerating its redox kinetics.
View Article and Find Full Text PDFJTO Clin Res Rep
October 2025
Clinical Research Center (CRC), Medical Pathology Center (MPC), Cancer Early Detection and Treatment Center (CEDTC), and Translational Medicine Research Center (TMRC), Chongqing University Three Gorges Hospital, Wanzhou District, Chongqing, People's Republic of China.
NUT carcinoma is a rare and highly aggressive malignancy characterized by rapid progression, resistance to conventional therapies, and an extremely poor prognosis. This report presents a 36-year-old patient with stage IIIB primary pulmonary NUT carcinoma who achieved remarkable clinical outcomes with NHWD-870 monotherapy, a novel BET inhibitor. After just 1 month of treatment, imaging revealed a partial response, and a complete response was achieved within 5 months.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
Beijing Key Laboratory of Chemical Power Source and Green Catalysis, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China.
Ce-doped cobalt boride (Ce-CoB) was synthesized a ZIF-67-derived boridation strategy, where Ce incorporation synergistically tunes the electronic structure to accelerate oxygen evolution kinetics. The Ce-CoB achieves an overpotential of 320 mV at 10 mA cm, outperforming benchmark CoB by 15.8% ( 350 mV) with remarkable robustness.
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