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Asynchronous interconnection is essential for integrating AC networks operating at different frequencies, typically 50 Hz and 60 Hz. This need arises from distributed power generation methods, including offshore renewable sources and diverse regional grid configurations. Advanced strategies are required to overcome these frequency differences and ensure uninterrupted power transfer. High-Voltage Direct Current (HVDC) transmission systems facilitate efficient power exchange, enhancing grid reliability and stability. This study focuses on optimizing the Proportional-plus-Integral (PI) controller parameters within a 20 MVA Voltage Source Converters (VSC)-based HVDC system to enable asynchronous interconnection between offshore and onshore AC networks. The offshore VSC regulates active and reactive power, while the onshore VSC controls DC voltage and reactive power. A vector control approach with symmetric optimum PI tuning is proposed for a comprehensive performance assessment of the VSC-based HVDC transmission system. The effectiveness of the tuned PI controller parameters is evaluated through four test cases using MATLAB/Simulink for offline simulation and Typhoon HIL604 for real-time validation. These cases involve abrupt changes in reference active and reactive power for the offshore VSC; and in reference reactive power and DC voltage for the onshore VSC. Results demonstrate rapid and satisfactory dynamic performance across all test cases, as evidenced by offline simulations and real-time validation. The validation highlights the effectiveness of the proposed control design with symmetric optimum PI tuning, confirming its ability to enhance the overall performance of the HVDC transmission system for efficient asynchronous interconnection.
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http://dx.doi.org/10.1016/j.heliyon.2024.e35624 | DOI Listing |
J Mater Chem B
September 2025
Dipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum - Università di Bologna, Via Piero Gobetti, 85, Bologna 40129, Italy.
Donor-acceptor-donor (D-A-D) thiophene-based compounds, characterized by thiophene as a donor unit and benzothiadiazole (Bz) as an acceptor, represent an emerging class of theranostic agents for imaging and photodynamic therapy. Here, we expand this class of molecules by strategically varying the position of the electron-accepting unit within the oligothiophene (OT) backbone structure, realizing a series of different push-pull architectures (A-D, D-A-D, and D-A). This rational design allows for precise modulation of key photophysical parameters, including absorption and emission spectra, molar absorption coefficient, charge separation, and frontier molecular orbitals.
View Article and Find Full Text PDFPLoS One
September 2025
Department of Environmental Health, Harvard T.H. Chan School of Public Health, Boston, Massachusetts, United States.
Background: Maternal childhood maltreatment has been associated with higher risk of adverse neurodevelopment in offspring. Chronic systemic inflammation has been associated with childhood maltreatment and has been identified as a gestational risk factor for adverse neurodevelopment in offspring. Thus, inflammation may be a mechanism by which maternal exposure to maltreatment affects offspring neurodevelopment.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Nuclear Power Institute of China, Chengdu, Sichuan 610065, P.R. China.
The low-carbon strategy mandates the sustainable remediation of hexavalent chromium (Cr(VI)) contamination, driving the demand for efficient eco-adsorbents. However, current research prioritizes adsorption performance, neglecting environmental trade-offs and quantum chemical mechanisms of Cr(VI) adsorption. Here, we pioneered the first density functional theory (DFT) exploration of Cr(VI) adsorption mechanisms across chitosan (CS), polydopamine (PDA), UiO-66-NH, and polyethylenimine.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China.
Disordered rock-salt LiVO (DRX-LVO) anode exhibits distinctive 3D Li percolation transport networks, which offers the unique advantage for ultra-charging. However, the existing chemical lithiation preparation routes not only pose safety risks due to the use of highly reactive reagents but also inevitably result in products with poor crystallinity. Investigating the origin, impact, and strategies for crystallinity degradation is pivotal for advancing the industrialization of chemical lithiation.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Department of Chemistry and Biochemistry, The University of Arizona, Tucson, AZ, 85721, USA.
A detailed understanding of the composition and polymerization mechanism of elemental sulfur remains a decades long unresolved question for modern chemistry. However, the dynamic nature of molten sulfur significantly complicates its accurate characterization. To overcome this challenge, we performed the first comprehensive molecular dynamics (MD) simulations using a ReaxFF reactive force field specifically parameterized to capture the complex ring-opening polymerization dynamics of elemental sulfur.
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