Effect of calcination temperature induced structural modifications on the photocatalytic efficacy of FeO-ZrO nanostructures: mechanochemical synthesis.

Water contamination due to organic pollutants is a challenging issue around the globe, and several attempts have been made to deal with this issue. Out of which, the semiconductor-based photocatalytic process had gained much attention and proved to be an efficient, easy, and economical process for the removal of organic dyes from aqueous solutions. For this purpose, the iron oxide-zirconium dioxide nanocomposite (FeO-ZrO NC) was prepared a simple mechanochemical process using a mortar and pestle, followed by a calcination process at 300, 600, and 900 °C. Different physicochemical analyses were carried out in order to investigate the successful synthesis of FeO-ZrO NC and the effect of temperature on the crystallinity, surface area, pore size, phase composition, sample morphology, and particle/crystallite size. The FeO-ZrO NCs were subjected to a photocatalytic test under solar light irradiation against fluorescein dye in an aqueous medium, and the photocatalytic performance was examined under the influence of calcination temperatures, pH, catalyst dose, and initial concentration. The stability of the FeO-ZrO NCs was also checked by recycling them for five reuse cycles.