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Objectives: In the cement production industry, exposure to airborne particulate matter is associated with a decline in lung function and increased airway symptoms. Exposure to clinker-the major constituent of cement and supposedly the cause of the observed adverse health effects-was determined recently in 15 cement production plants located in 8 different countries (Estonia, Greece, Italy, Norway, Sweden, Switzerland, Spain, Turkey). It was shown that the median clinker abundance in the thoracic fraction varied between approximately 20% and 70% for individual plants. The present study complements the previous work by investigating the significance of job function as a determinant of clinker exposure.
Methods: The elemental composition (water and acid-soluble fractions separately) of 1,227 personal thoracic workplace samples was analyzed by positive matrix factorization (PMF) to determine the contribution of different sources to the composition of airborne particulate matter and to quantify the clinker content.
Results: Median thoracic mass air concentrations varied for individual job functions between 0.094 and 12 mg/m3 (estimated separately for different plants). The PMF 5-factor solution yielded median relative clinker abundances in the personal thoracic samples between 7.6% and 81% for individual job functions. Thoracic clinker air concentrations are highest for cleaning, production, and maintenance work, and lowest for administration and other work. Foremen and laboratory personnel show intermediate exposure levels. The plant was found to have a much higher contribution to the total variance of the thoracic clinker air concentrations than the job function. Thoracic clinker air concentrations (medians between 0.01 and 5.5 mg/m3) are strongly correlated with the thoracic mass air concentrations and to a lesser extent with the relative clinker abundance in an aerosol sample.
Conclusions: Job function is an important predictor of exposure to clinker in the cement production industry. As clinker is suspected to be the causal agent for the observed adverse health effects among cement production workers, the clinker air concentration may be a better exposure metric than thoracic air mass concentration despite the strong correlation between the two. Reduction strategies should focus on the most exposed job categories cleaning, production, and maintenance work.
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http://dx.doi.org/10.1093/annweh/wxae022 | DOI Listing |
ACS Omega
September 2025
Changsha Research Institute of Mining and Metallurgy CO., LTD, Changsha 410012, Hunan, China.
The long-term accumulation of electrolytic manganese residue leads to pollution issues related to NH -N and Mn. Although various methods exist to address the pollution caused by NH -N and Mn, existing hazard-free treatment methods do not consider the subsequent utilization of the electrolytic manganese residue. Meanwhile, resource recovery methods face challenges due to the complex salt structures present in electrolytic manganese residue.
View Article and Find Full Text PDFEnviron Res
September 2025
Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources, Ministry of Education, Wuhan University of Technology, Wuhan, Hubei 430070, China; School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan, Hubei 430070, China. Electronic address: yubiao
In order to promote the development and application of low-carbon cement varieties and the recycling of industrial solid waste, this study used iron tailings and fluorogypsum to prepare iron-rich belite-sulfoaluminate cement (I-BCSA). The suitable conditions for the preparation of I-BCSA in this system were with an excessive addition of 6 wt% of SO in the raw meal, at a calcination temperature of 1250 °C for 1.5 h, and an added-gypsum content of 15 wt%.
View Article and Find Full Text PDFJ Hazard Mater
August 2025
Department of Environmental Science, Kangwon National University, Chuncheon, Gangwon-do 24341, Republic of Korea; Interdisciplinary Program in Earth Environmental System Science & Engineering, Kangwon National University, Chuncheon, Gangwon-do 24341, Republic of Korea; Gangwon particle pollution res
This study evaluates the oxidative potential (OP) of PM and its chemical drivers across three contrasting environments in South Korea: a residential area, a cement factory, and a charcoal kiln facility. Mass-normalized OP (OPm, reflecting intrinsic particle reactivity) ranged from 9.5 to 13.
View Article and Find Full Text PDFPLoS One
September 2025
School of Civil Engineering, Guizhou University, Guiyang, Guizhou Province, China.
Phosphogypsum is an acidic solid waste mainly composed of CaSO₄-2H₂O by-products of the wet process phosphoric acid industry, which has the characteristics of high impurity content, poor stability of stockpiling, but can be utilized in a resourceful way. Phosphogypsum waste utilization can reduce environmental pollution, save resources and create economic value. In order to investigate the fatigue characteristics and the mechanism of dynamic strength change of cement-phosphogypsum-red clay under wet and dry cycles, the cumulative deformation characteristics and the rule of change of critical dynamic stress of the mixed materials were investigated by dynamic triaxial fatigue test, SEM and XRD test, and the mechanism of dynamic strength change was analyzed according to the microstructure and the chemical mineral composition of the mixed materials.
View Article and Find Full Text PDFEnviron Geochem Health
September 2025
Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences, Beijing, China.
With the rapid development of industrialization in China, more and more industrial solid wastes (ISWs) are generated in industrial production processes. Under the pressure for safe disposals or utilization of ISWs as resources, and the demand for soil pollution remediation in China, there have been attempts to incorporate ISWs into agricultural land as soil amendments, while the environmental impacts of ISWs applied on agricultural land have aroused great concerns. This paper presents a comprehensive overview regarding the environmental risks from impacts of 7 types of ISWs (including blast furnace slag, steel slag, magnesium slag, coal-fired flue gas desulfurization gypsum, phosphogypsum, calcium carbide slag, and ammonia-soda residue) applied on agricultural land.
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