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Article Abstract
A 6-Ti-substituted polyoxometalate, (NH)CsNaH[Cs@(TiGeMoO)]·34HO (), was synthesized by reacting (NH)MoO·4HO, GeO, and TiOSO through the conventional aqueous method. Polyanion is composed of three {TiGeMo} segments linked by Ti-O-Ti linkages and shows a trefoil-shaped structure. Furthermore, one Cs cation is encapsulated in the cavity of . Notably, it possesses the highest number of Ti centers among the reported polyoxomolybdates. In addition, serving as a high-efficiency heterogeneous catalyst, enables the conversion of methyl phenyl sulfide within 20 min, yielding 96.4% of the corresponding sulfoxide with good recyclability.
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