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The aminated sodium lignosulfonate (AELS) was prepared through a Mannich reaction and characterized via FT-IR, TG, SEM and XPS in this study. Subsequently, the adsorption capacity of AELS for methyl blue (MB) was evaluated under various conditions such as pH, adsorbent dosage, contact time, initial concentration and temperature. The adsorption kinetics, isotherms and thermodynamics of AELS for methyl blue were investigated and analyzed. The results were found to closely adhere to the pseudo-second-order kinetic model and Langmuir isotherm model, suggesting a single-molecular-layer adsorption process. Notably, the maximum adsorption capacity of AELS for methyl blue (153.42 mg g) was achieved under the specified conditions ( = 298 K, = 0.01 g, pH = 6, = 25 mL, = 300 mg L). The adsorption process was determined to be spontaneous and endothermic. Following five adsorption cycles, the adsorption capacity exhibited a minimal reduction from 118.99 mg g to 114.33 mg g, indicating good stability. This study contributes to the advancement of utilizing natural resources effectively and sustainably.
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http://dx.doi.org/10.3390/ma17051046 | DOI Listing |
Int J Biol Macromol
September 2025
State Key Laboratory of Bio-Fibers and Eco-Textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China. Electronic address:
Biomass xerogels with porous structures fabricated in ambient conditions possess great advantages including scalability, biocompatibility, and biodegradability, thus have shown demonstrated potential in various fields. However, disadvantages such as poor moisture resistance, poor mechanical properties, and low production efficiency challenge their practical applications. In this study, microfibers self-assembled from sodium alginate and chitosan are adopted to facilely fabricate biomass porous xerogel membranes with a fast one-step solvent-exchange, which is achieved due to the low crystallinity and small aspect ratio of the microfibers.
View Article and Find Full Text PDFInorg Chem
August 2025
Department of Chemistry, Dibrugarh University, Assam India 786004.
Conductive metal organic frameworks (MOFs) are considered as next-generation conducting materials. However, imparting conductivity to this class of materials faces significant challenges owing to their inherently insulating nature. Therefore, herein, a series of isostructural conductive bimetallic MOFs with the structural formula {[(CH)NH][MnCo(HCOO)]} ( = 1, = 0.
View Article and Find Full Text PDFMaterials (Basel)
July 2025
Departamento de Física, Universidade Federal do Espírito Santo, Vitória 29075-910, Brazil.
The contamination of aquatic systems by industrial dyes, particularly methylene blue (MB), presents a significant environmental challenge due to their chemical stability and toxicity. In this study, the development and application of a novel magnetic nanohybrid comprising multiwall carbon nanotubes (MWCNTs) functionalized with maghemite (γ-FeO) nanoparticles biosynthesized using extract (denoted MWNT-NPE) is reported. The material was thoroughly characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), Vibrating Sample Magnetometer (VSM), and Fourier-Transform Infrared (FTIR) techniques, revealing high crystallinity, mesoporosity, and superparamagnetic behavior.
View Article and Find Full Text PDFJ Environ Manage
July 2025
Research and Development Center for Watershed Environmental Eco-Engineering, Advanced Institute of Natural Sciences, Beijing Normal University, Zhuhai, 519087, PR China; School of Environment, Beijing Normal University, Beijing, 100875, PR China. Electronic address:
Membrane technology can realize the sustainable management of textile wastewater through dye/salt separation, but its practical implementation has long been hampered by membrane fouling. This work was to develop a novel carbon nitride based two-dimensional (2D) self-assembled membrane for efficient dye/salt separation with excellent photocatalytic self-cleaning performance toward azo dyes (e.g.
View Article and Find Full Text PDFInt J Biol Macromol
June 2025
College of Materials Science and Engineering, Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, Guilin University of Technology, Guilin 541004, China; Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Util
The selective removal of specific dyes from mixed dye solutions faces great challenges. This work fabricated an eco-friendly, structure-controlled montmorillonite/cellulose-chitosan foam (NaMt/CNC-CS) through Pickering emulsion templating combined with freeze-drying technology for selective adsorption of methyl blue (MB). Under the conditions of pH 3 and an initial MB concentration of 60 mg/L, the NaMt/CNC-CS achieved a MB removal efficiency of 99.
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