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The present work investigated the effect of destabilization time on the mechanical properties and microstructure evolution of high chromium cast iron, and scanning electron microscopy and electron probe microanalysis techniques were employed. The results show that the hardness of hypoeutectic high chromium cast iron is related to the size and volume fraction of secondary carbides precipitated from the matrix. The hardness of the alloy continues to rise due to the continuous increase of the volume fraction of the secondary carbide at the initial stage of destabilization. The alloy reaches its peak hardness value at 950 °C and 1000 °C for 1 hour holding time. The solid solubility of carbon and alloying elements in the matrix increases as the holding time extends, resulting in a large number of carbides redissolved into the matrix, making the hardness of the alloy decrease; the hardness of the alloy at 14 h is less than that at 10 min. Under 1050 °C, the size and density of the secondary carbide increase significantly; extending the holding time will lead to the continuous reduction of the carbide rod that provides strength, thus, the hardness curve shows a downward trend.
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http://dx.doi.org/10.1039/d4ra01247j | DOI Listing |
Integr Environ Assess Manag
September 2025
School of Public Health, Taipei Medical University, New Taipei City, 235040Taiwan.
Incorporating bioaccessibility into health risk assessments enhances the accuracy of exposure estimates for heavy metal (HM) pollution, supports targeted remediation, and informs public health and policy decisions, particularly for vulnerable populations. Because HM bioaccessibility depends on local soil and geographic characteristics, identifying its relationship with soil properties is crucial for assessing soil pollution potential. Although HM concentrations can be measured relatively easily, bioaccessibility requires complex laboratory procedures, limiting routine applications in regulatory contexts.
View Article and Find Full Text PDFAnal Chim Acta
November 2025
Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, Key Laboratory of Nanobiosensor Analysis, College of Chemistry and Materials, Nanning Normal University, Nanning, 530001, PR China. Electronic address:
Background: Hexavalent chromium ions (Cr(VI)), a notorious toxic heavy metal pollutant with proven carcinogenicity, endangers human health and the environment. Meanwhile, l-ascorbic acid (L-AA), a vital biological antioxidant, has abnormal levels closely tied to various diseases. Developing efficient synchronous detection methods for these two key analytes is of great value in clinical and environmental monitoring.
View Article and Find Full Text PDFChemistry
September 2025
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, China.
This study introduces the HydroTherm-Flow Smart Window (HTF Window), the first groundbreaking integration of thermochromic windows and Fe-Cr redox flow batteries (Fe-Cr RFBs), achieving dual functionalities of dynamic solar modulation-via dual-band (visible + near-infrared, NIR) modulation-and high-efficiency energy storage in a single component. Leveraging tunable hydroxypropyl cellulose (HPC) hydrogels, it enables ultrafast optical switching and autonomous nighttime opacity, overcoming the slow response and privacy limitations of conventional thermochromic systems. By repurposing the window as a compact electrolyte reservoir, it reduces the RFB spatial footprint while enhancing ionic conductivity by 30% via hydrogel "ion highways," achieving 77% energy efficiency with a 40% reduction in the solar heat gain coefficient.
View Article and Find Full Text PDFJ Arthroplasty
September 2025
Implant Research Core, School of Biomedical Engineering, Science, and Health Systems, Drexel University, Philadelphia, PA, USA.
Background: In a subset of total hip arthroplasty (THA) patients, investigators associate metal release with biological complications. Comparatively, metal release in the knee is less understood. In this study, we systematically reviewed total knee arthroplasty (TKA) metal release studies.
View Article and Find Full Text PDFSmall
September 2025
Department of Semiconductor Physics and Institute of Quantum Convergence Technology, Kangwon National University, Chuncheon, 24341, South Korea.
2D van der Waals ferromagnets hold immense promise for spintronic applications due to their controllability and versatility. Despite their significance, the realization and in-depth characterization of ferromagnetic materials in atomically thin single layers, close to the true 2D limit, has been scarce. Here, a successful synthesis of monolayer (ML) 1T-CrTe is reported on a bilayer graphene (BLG) substrate via molecular beam epitaxy.
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