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Recently, long persistent phosphors (LPPs) have attracted significant attention as promising candidates for biomedical applications. However, the serious decrease in luminescence intensity in tissue still remains a major challenge. Therefore, exploring more competitive LPPs and achieving reproducible tissue imaging is crucial. In this study, a new series of near-infrared (NIR) phosphors La Ga Sn O :xCr (x = 0.005-0.05) were synthesized using a high-temperature solid-state method. The as-synthesized samples were characterized using X-ray diffraction, diffuse/photoluminescence spectroscopy, fluorescence decay curves, and thermoluminescence spectroscopy. Upon excitation with ultraviolet light, strong emission bands were observed in the range 600-1200 nm with an optimal doping concentration of x = 0.02 mol. Moreover, La Ga SnO :Cr exhibits persistent luminescence due to the presence of suitable energy traps, which prompted the phosphor to emit NIR light even after the removal of the excitation source.
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http://dx.doi.org/10.1002/bio.4674 | DOI Listing |
J Mater Chem B
September 2025
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China.
Adenosine triphosphate (ATP) is a critical biomolecule in cellular energy metabolism, with abnormal levels in the bloodstream linked to pathological conditions such as ischemia, cancer, and inflammatory disorders. Accurate and real-time detection of ATP is essential for early diagnosis and disease monitoring. However, conventional biochemical assays and other techniques suffer from limitations, including invasive sample collection, time-consuming procedures, and the inability to provide dynamic, monitoring.
View Article and Find Full Text PDFJ Mater Chem B
September 2025
Key Laboratory of Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China.
Perylene diimide (PDI) radical anions have attracted increasing attention as hypoxia-responsive photothermal agents due to their strong near-infrared (NIR) absorption and efficient photothermal conversion. However, their biomedical application is often limited by aggregation-induced quenching and poor structural tunability. In this work, we report a rationally engineered four-arm PDI derivative (PDI-4Alky·4Cl) bearing terminal alkyne groups, which not only suppresses π-π stacking steric and electrostatic repulsion, but also serves as a versatile molecular scaffold for further functionalization.
View Article and Find Full Text PDFAnal Methods
September 2025
Henan Linker Technology Key Laboratory, College of Advanced Interdisciplinary Science and Technology (CAIST), Henan University of Technology, Zhengzhou 450001, China.
Salicylic acid (SA) is a critical phytohormone involved in plant growth, development, and defense responses, making its precise quantification essential for both agricultural management and environmental monitoring. Here, we report a novel label-free near-infrared aptasensor (NIRApt) for the rapid and sensitive detection of SA, utilizing a rationally selected triphenylmethane (TPM) dye. Through systematic screening, ethyl violet (EV) was identified as the optimal fluorophore, showing pronounced fluorescence enhancement upon binding to a SA-specific aptamer.
View Article and Find Full Text PDFNanoscale
September 2025
Université Paris Cité, Laboratoire ITODYS, CNRS, F-75006 Paris, France.
Aluminum (Al) is a cost-effective alternative to noble metals for plasmonics, particularly in the ultraviolet (UV) and visible regions. However, in the near-infrared (NIR) region, its performance is hindered by interband transitions (IBTs) at around 825 nm, leading to increased optical losses and broad resonances. Surface lattice resonances (SLRs) offer a promising solution by enhancing the plasmonic quality factor (-factor) through coherent coupling of localized surface plasmon (LSP) modes with Rayleigh anomalies.
View Article and Find Full Text PDFJ Dairy Res
September 2025
Secretaría de Ciencia, Humanidades, Tecnología e Innovación, Insurgentes, Ciudad de México, México.
Changes in waxed dry cheese during the ripening process, over periods of 7 and 30 days, were analysed using near-infrared spectroscopy (FT-NIR) and mid-infrared spectroscopy (FT-MIR) by attenuated total reflection (ATR). FT-NIR was employed to determine the proximate composition of the cheese (protein, fat, moisture, total solids, and salt content), identifying changes directly associated with the ripening process. FT-MIR data were used to identify spectral bands associated with chemical changes occurring during the cheese maturation.
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