Recent developments in lignin-based fluorescent materials.

Biomass-based fluorescent materials are an alternative to plastic-based materials for their multifunctional applications. Lignin, an inexpensive and easily available raw material, demonstrates outstanding environment-responsive properties such as pH, metal ions, dyes sensing, bioimaging and so on. To date, only a little work has been reported on the synthesis of lignin-based fluorescent materials. In this review report, synthetic approaches and light-responsive applications of lignin-based fluorescent carbon dots and other materials are summarized. The results reveal that lignin-based fluorescent carbon dots are prepared by hydrothermal method, exhibit small size <10 nm, reveal significant quantum yield, biocompatibility, non-toxicity, photostability and display substantial tunable emission and can be efficiently employed for sensing, bioimaging and energy storage applications. Finally, the forthcoming challenges, investigations, and options open for the chemical and/or physical modification of lignin into fluorescent materials for future applications are well-addressed. To our knowledge, this is the first comprehensive review report on lignin-based fluorescent materials and their light-responsive applications. In addition, this review will attract remarkable consideration and thrust for the researchers and biochemical technologists working with the preparation of lignin-based fluorescent materials for broad applications.