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Flotation separation of chalcopyrite from pyrite using lime or cyanides as depressants results in serious problems, such as the blockage of pipelines and environmental pollution. Eco-friendly organics are a future trend for beneficiation plants. In this research, the eco-friendly organic depressant sodium humate (SH) was chosen as a depressant to separate chalcopyrite from pyrite by flotation. The results indicated that SH could selectively depress pyrite owing to the oxidation species (FeOOH, Fe(SO)) on its surface. The oxidation species were the adsorption sites for the COO in the SH structure and impeded the subsequent collector potassium ethyl xanthate (KEX) adsorption. However, chalcopyrite was slightly oxidized with fewer oxidation species for SH adsorption, and KEX could be adsorbed and functioned effectively. This research suggested that SH could be an effective and eco-friendly depressant in chalcopyrite-pyrite flotation separation, which had potential use in the industry.
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http://dx.doi.org/10.1021/acsomega.3c07539 | DOI Listing |
Langmuir
July 2025
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Metal Resources, Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650093, PR China.
The efficient flotation separation between chalcopyrite and pyrite is considered challenging under weak alkaline conditions due to their similar floatability characteristics. In this work, based on the differences in the chemical valence states of Fe atoms on chalcopyrite and pyrite, an innovative depressant system combining sodium sulfide (NaS) and proanthocyanidins (PC) was proposed. In artificial mixed ore tests, compared with a single PC, a higher separation efficiency between chalcopyrite and pyrite is achieved when the combined depressants 20 mg/L NaS and 40 mg/L PC are employed.
View Article and Find Full Text PDFFront Microbiol
May 2025
Institute for Biological and Medical Engineering, Schools of Engineering, Medicine & Biological Sciences, Pontificia Universidad Católica de Chile, Santiago, Chile.
Biomining is a sustainable alternative to conventional mineral processing that uses acidophilic microorganisms to catalyze the extraction of valuable metals from sulfide minerals. Mixed microbial consortia composed of moderate thermophiles such as and some species improve metal extraction efficiency at higher temperatures compared to pure cultures of mesophiles. However, quorum sensing (QS), which regulates microbial interactions and likely influences bioleaching performance, has not been studied in these species.
View Article and Find Full Text PDFBiology (Basel)
April 2025
State Key Laboratory of Submarine Geoscience, Second Institute of Oceanography, Ministry of Natural Resources, Hangzhou 310012, China.
The weathering of seafloor hydrothermal sulfides is facilitated by microbial activities, yet the specific mechanisms of different sulfide types are not well understood. Previous studies have primarily been carried out under laboratory conditions, making it difficult to accurately replicate the complex in situ conditions of deep-sea hydrothermal fields. Herein, we deployed two well-characterized pyrite (Py)-dominated and chalcopyrite (Ccp)-dominated sulfide slices, which were placed 300 m from an active venting site in the Wocan-1 hydrothermal field (Carlsberg Ridge, Northwest Indian Ocean) for an 18-month in situ incubation experiment.
View Article and Find Full Text PDFChemistryOpen
May 2025
Sustainable and Innovative Minerals and Metals Extraction Technology (SIMMET) Group, School of Chemical and Metallurgical Engineering, University of the Witwatersrand, Private Bag X3, Wits, 2050, South Africa.
Understanding the oxidation of sulfidic minerals, especially those of pyrite and chalcopyrite, under acidic conditions has important outcomes, such as exposing any encapsulated gold not recovered by traditional cyanidation processes. This study focused on the electrochemical oxidation of pyrite and chalcopyrite in a 0.5 M nitric acid solution.
View Article and Find Full Text PDFWorld J Microbiol Biotechnol
April 2025
Laboratory of Applied and Basic Microbiology, Department of Biology, Faculty of Chemistry and Biology, University of Santiago of Chile (USACH), Av. Libertador Bernardo O'Higgins 3363, Santiago, Chile.
Acidithiobacillus ferrooxidans is a chemolithoautotrophic acidophilic bacterium belonging to microbial communities involved in sulfide ore bioleaching. This microorganism possesses redundancy of genes encoding ATP-independent chaperone holdases like Hsp20 (hps20.1, hsp20.
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