Effects and mechanism on cadmium adsorption removal by CaCl-modified biochar from selenium-rich straw.

Bioresour Technol

School of Materials Science and Engineering, Yangtze Normal University, Chongqing 408100, China; School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China.

Published: February 2023


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Article Abstract

As every-one knows, cadmium contamination poses a significant and permanent threat to people and aquatic life. Therefore, research on how to remove cadmium from wastewater is essential to protect the natural environment. In this study, agricultural and forestry waste straw sprayed with selenium-enriched foliar fertilizer was prepared as biochar, which was altered by calcium chloride (CaCl) to remove Cd from water. The outcomes demonstrated that biochar generated by pyrolysis at 700 °C (BC700) had the best adsorption effect. Secondly, pseudo-second-order kinetics and Langmuir adsorption models were used to predict the Cd adsorption. Finally, electrostatic adsorption, ion exchange, and complexation of oxygen functional groups (OFGs) were demonstratedto be the main adsorption mechanisms. These conclusions indicate that selenium-rich straw biochar is a novel adsorbent for agroforestry waste recovery. Meanwhile, this work will offer a promising strategy for the overall utilization of rice straw.

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http://dx.doi.org/10.1016/j.biortech.2022.128563DOI Listing

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Effects and mechanism on cadmium adsorption removal by CaCl-modified biochar from selenium-rich straw.

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