3D nanocrystalline metal-organic framework materials for the improved output performance of triboelectric nanogenerators.

Triboelectric nanogenerators (TENGs) based on contact electrification and electrostatic induction can effectively convert low-frequency mechanical energy into electrical energy and has attracted considerable attention. However, the low current output performance seriously hinders the wide application of TENGs. Herein, a 3D nanocrystalline metal-organic framework (Cd-MOF) with a specific structure and morphology was reasonably designed as a high-performance triboelectric positive electrode material. The triboelectric test results showed that the maximum instantaneous short-circuit current of Cd-MT was 55.32 μA and the stable output performance maintained a long-term continuous operation for 10 000 s. The peak values of the charge density and electric power density were 102.39 μC m and 2451.04 mW m, respectively. In addition, the Cd-MT could quickly fully charge commercial capacitors and light a large number of LED lamps. This work provides a new idea for the development and design of functional MOF triboelectric materials.