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Embedded three-dimensional (3-D) metal-insulator-metal (MIM) decoupling capacitors with high-κ dielectric films of high capacitance and long-life time are increasingly needed on integrated chips. Towards achieving better electrical performance, there is a need for investigation into the influence of the variation in atomic layer deposition (ALD) parameters used for thin high-κ dielectric films (10 nm) made of AlO-doped ZrO. This variation should always be related to the structural uniformity, the electrical characteristics, and the electrical reliability of the capacitors. This paper discusses the influence of different Zr precursor pulse times per ALD cycle and deposition temperatures (283 °C/556 K and 303 °C/576 K) with respect to the capacitance density (C-V), voltage linearity and leakage current density (I-V). Moreover, the dielectric breakdown and TDDB characteristics are evaluated under a wide range of temperatures (223-423 K).
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http://dx.doi.org/10.3390/ma15238325 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Core Manufacturing Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
The direct deposition of piezoelectric ceramic thin films onto metal foils has become a significant challenge due to the increasing demand for embedded decoupling capacitors, nanogenerators, and flexible piezo-sensors. However, traditional thermal sintering (TS) methods present several issues for metal foils, including alterations in mechanical properties, the formation of wrinkles, and the need for precise control over the sintering atmosphere to prevent oxidation. In this study, we successfully crystallized BaTiO on a Ni foil under atmospheric conditions, mitigating thermal damage to the foil through a hybrid-solution-incorporated photoassisted chemical solution deposition (HS-PCSD) method.
View Article and Find Full Text PDFJ Magn Reson
August 2025
Vanderbilt University Institute of Imaging Science, Vanderbilt University Medical Center, Nashville, TN 37232, USA; Department of Electrical and Computer Engineering, Vanderbilt University, Nashville, TN 37232, USA; Department of Radiology and Radiological Sciences, Vanderbilt University Medical Cen
Flexible RF coils enhance patient comfort and increase filling factors, making them attractive for MRI. However, achieving first-mode resonance at 7 T for large-diameter, flexible coils remains a challenge. We present a coaxial capacitor (COCA) coil, which can be 10 cm in diameter and still operates in the first resonant mode at 298 MHz.
View Article and Find Full Text PDFSci Rep
August 2025
Electrical Engineering Department, Faculty of Engineering, Port Said University, Port Said, Egypt.
In this paper, a novel wide range microinverter circuit that can interface with a single-phase grid and operates without a transformer is presented. The proposed topology uses six switches: two of those switches function at line frequency every half cycle while the other switches function at high switching frequency. In the proposed topology, the circuit functions in discontinuous conduction mode (DCM) across all possible operating conditions, ensuring high gain and minimal switching losses.
View Article and Find Full Text PDFIEEE J Solid-State Circuits
August 2025
Department of Electrical and Computer Engineering, Worcester Polytechnic Institute, Worcester, MA 01609 USA.
This article presents a novel technique that is immune to offset, enabling precise determination of the lifetime of luminescent materials. The technique is specifically applied to measure transcutaneous oxygen, an indicator of oxygen that diffuses through the skin and reflects arterial oxygen levels. Unlike intensity-based measurements, lifetime-based luminescence measurements are superior because they decouple oxygen information from confounding factors.
View Article and Find Full Text PDFSmall
September 2025
Nanotechnology and Integrated Bioengineering Centre (NIBEC), School of Engineering, Ulster University, 2-24 York Street, Belfast, Northern Ireland, BT15 1AP, UK.
When a liquid contacts a charged solid surface, counterions in the liquid accumulate near the interface-a process traditionally described by models such as Helmholtz, Stern, and Debye-Hückel. However, these frameworks overlook the complex interplay between inertia and surface charge, and they simplify ions as mere point charges. This study employs vibrating solid surfaces to decouple and investigate the effects of inertia, ion-slipping, and electrostatic interactions at the molecular scale.
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