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Energy harvesting devices made of piezoelectric material are highly anticipated energy sources for power wireless sensors. Tremendous efforts have been made to improve the performance of piezoelectric energy harvesters (PEHs). Noticeably, topology optimization has shown an attractive potential to design PEHs with enhanced energy conversion efficiency. In this work, an alternative yet more practical design objective was considered, where the open-circuit voltage of PEHs is enhanced by topologically optimizing the through-thickness piezoelectric material distribution of plate-type PEHs subjected to harmonic excitations. Compared to the conventional efficiency-enhanced designs, the open-circuit voltage of PEHs can be evidently enhanced by the proposed method while with negligible sacrifice on the energy conversion efficiency. Numerical investigations show that the voltage cancellation effect due to inconsistent voltage phases can be effectively ameliorated by optimally distributed piezoelectric materials.
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http://dx.doi.org/10.3390/ma15134423 | DOI Listing |
J Colloid Interface Sci
September 2025
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China. Electronic address:
Moisture-driven energy generators (MEGs) represent a renewable energy technology, yet challenges such as environmental humidity dependence and transient power generation behavior hinder their practical applications. Herein, a high-performance bilayer MEG is developed by integrating MXene-impregnated paper with a polyacrylamide (PAM) hydrogel to realize environmental tolerance and sustained power generation. Electronegative MXene and paper with 3D porous structure synergistically facilitate selective transport of positive charge, while the hydrogel serves as a water reservoir to provide a moist environment and migratory ions.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Hebei Key Laboratory of Optic-Electronic Information and Materials, College of Physics Science and Technology, Hebei University, Baoding 071002, P. R. China.
A highly sensitive, self-powered position-sensitive detector (PSD) based on a PEDOT:PSS/Si heterojunction is prepared. Band structure optimization via FS-300 additive doping significantly enhances the built-in electric field, achieving a maximum open-circuit voltage of 0.45 V (0.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China.
Additive assisted strategies play a crucial role in optimizing the morphology and improving the performance of organic solar cells (OSCs), yet the molecular-level mechanisms remain unclear. Here, we employ molecular dynamics (AIMD) and density functional theory (DFT) to elucidate the influence of typical additives of 1,8-diiodooctane (DIO) and 3,5-dichlorobromobenzene (DCBB) on molecular packing, electronic structures, and charge transport. It can be observed that both additives can enhance the stacking properties of the donor and acceptor materials, yet they have different effects on the local electrostatic environment.
View Article and Find Full Text PDFInorg Chem
September 2025
College of Chemistry and Chemical Engineering, Key Laboratory of Shandong Provincial Universities for Functional Molecules and Materials, Qingdao University, Qingdao, Shandong 266071, P. R. China.
Molecular piezoelectrics have garnered significant attention in energy harvesting and sensing fields due to their high intrinsic piezoelectricity, low elastic properties, and excellent solution processability. Recent efforts have primarily focused on rationally tuning the piezoelectric performance of these materials through the molecular predesign of organic components. However, the regulation of piezoelectric properties via the central metal ion has remained relatively underexplored.
View Article and Find Full Text PDFNat Commun
September 2025
School of Materials Science and Engineering, Nanyang Technological University, Singapore, Singapore.
The photovoltaic performance of CuZnSn(S,Se) is limited by open-circuit voltage losses (ΔV) in the radiative (ΔV) and non-radiative (ΔV) limits, due to sub-bandgap absorption and deep defects, respectively. Recently, several devices with power conversion efficiencies approaching 15% have been reported, prompting renewed interest in the possibility that the key performance-limiting factors have been addressed. In this work, we analyze the sources of ΔV in these devices and offer directions for future research.
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