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Conventionally, the realization of polarization transformation and wavefront manipulation in metasurfaces relies on the Pancharatnam-Berry (PB) phase together with the dynamic phase. However, the reported polarization transformation and wavefront manipulation were limited to spin-dependent wavefront manipulation for circular polarization (CP). To obtain more abundant functions, we propose a novel technology that relies on the dynamic phase with a spatial interleaving unit arrangement. With the functions of a quarter wave plate, the metasurfaces we designed can achieve multiple wavefront manipulations which are not only for the spin polarization transformation but also for the linear polarization transformation. Specifically, we design a bifocal metasurface, which can focus on one circularly polarized component as a point and spin-opposite component as a vortex under the linearly polarized (LP) incidence. With the further adjustment of the unit arrangement, the left-hand circularly polarized (LCP) and right-hand circularly polarized (RCP) components under the LP incidence can be refocused on the same point and then composited, resulting in a new LP exit wave. Furthermore, we prove theoretically that the desired -LP component and -LP component under the arbitrary CP incidence can also be manipulated independently. We believe that the versatility of this method will provide a novel platform for the development of terahertz integrated photonics.
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http://dx.doi.org/10.1039/d1nr03388c | DOI Listing |
Phys Rev Lett
August 2025
University of Southern Denmark, Centre for Nano Optics, Campusvej 55, Odense M DK-5230, Denmark.
Controlling the spontaneous emission of nanoscale quantum emitters (QEs) is crucial for developing advanced photon sources required in many areas of modern nanophotonics, including quantum information technologies. Conventional approaches to shaping photon emission are based on using bulky configurations, while approaches recently developed in quantum metaphotonics suffer from limited capabilities in achieving desired polarization states and directionality, failing to provide on-demand photon sources tailored precisely to technological needs. Here, we propose a universal approach to designing versatile photon sources using on-chip QE-coupled meta-optics that enable direct transformations of QE-excited surface plasmon polaritons into spatially propagating photon streams with arbitrary polarization states, directionality, and amplitudes via both resonance and geometric phases supplied by scattering meta-atoms.
View Article and Find Full Text PDFBiomater Res
September 2025
Department of Vascular Surgery, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai 200011, China.
Atherosclerosis is the leading cause of global cardiovascular morbidity and mortality associated with inflammatory and immunological mechanisms. Immunotherapy has demonstrated promising efficacy in the management of atherosclerosis. Nevertheless, certain immunotherapeutic approaches are associated with limitations, including suboptimal efficacy and non-negligible adverse effects.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080-3021, United States.
The direct transformation of C-H bonds into C-C bonds via cross-dehydrogenative coupling (CDC) represents a powerful strategy in synthetic chemistry, enabling streamlined bond construction without the need for prefunctionalized substrates. While traditional CDC approaches rely on polar mechanisms and preactivation of one of the C-H partners, recent advances have introduced radical-based strategies that employ a hydrogen atom transfer (HAT) approach to access carbon-centered radicals from unactivated substrates. Herein, we report a nickel-catalyzed CDC reaction between aldehydes and alkenes for the synthesis of skipped enones, leveraging aryl radicals as intermolecular HAT agents.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
University of Ljubljana, Faculty of Pharmacy, Aškerčeva 7, 1000, Ljubljana, Slovenia. Electronic address:
Monoclonal antibodies (mAb) have transformed modern medicine, offering targeted therapies for cancer, autoimmune disorders, and infectious diseases. To enhance patient convenience, subcutaneous administration is increasingly prioritized, requiring highly concentrated formulations. However, high viscosity of these formulations hinders manufacturability, injectability, and stability.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
State Key Laboratory of Chemistry for NBC Hazards Protection, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China.
The activation of methane and other gaseous hydrocarbons at low temperature remains a substantial challenge for the chemistry community. Here, we report an anaerobic photosystem based on crystalline borocarbonitride (BCN) supported Fe-O nanoclusters, which can selectively functionalize C-H bonds of methane, ethane, and higher alkanes to value-added organic chemicals at 12 °C. Scanning transmission electron microscopy and X-ray absorption spectroscopy corroborated the ultrafine FeOOH and FeO species in Fe-O clusters, which enhanced the interfacial charge transfer/separation of BCN as well as the chemisorption of methane.
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