Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Single-atom catalysis has become a new branch in heterogeneous catalysis. Although the naturally produced SiO -based materials are abundant and stable, fabrication of single-atom catalysts on such supports with high loading remains as a formidable challenge due to the lack of bonding sites to anchor the isolated metal species. Herein, modifying the diatomite, a kind of pure SiO mineral, with CeO nanoparticles is demonstrated to increase the defect sites on the support. The enhanced metal-support interaction maintains the atomic dispersion of Pt species with above 1 wt.% loading, exhibiting good performance in the selective hydrogenation of phenylacetylene to styrene.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/asia.202100730 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Fullerenes as Unique Modular Carbon Building Blocks for Advanced Electrocatalysis.
Small Methods
September 2025
State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Electrocatalytic reactions play a pivotal role in advancing sustainable energy technologies, particularly in the conversion of renewable resources into clean fuels. Achieving high-efficiency and durable electrocatalysts is essential for overcoming kinetic barriers in key processes. In this context, fullerenes have emerged as promising building blocks for catalyst design, owing to their unique structural and electronic characteristics.
View Article and Find Full Text PDFDefect-mediated high loading metal single-atom catalysts direct oxygen reduction reaction selectivity to HO production.
J Colloid Interface Sci
August 2025
State Key Laboratory of Water Pollution Control and Green Resource Recycling, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, China. Electronic address:
Transition metal single-atom catalysts (TM-SACs) have emerged as promising electrocatalysts for the two-electron oxygen reduction reaction (2eORR) due to their exceptional atomic utilization efficiency and tunable electronic structures. Nevertheless, the practical application of TM-SACs is constrained by their relatively low metal loading, which adversely affects their catalytic performance. Herein, we developed a universal defect-mediated strategy to fabricate TM-SACs with high metal loading.
View Article and Find Full Text PDFUnveiling Structure-Activity Relationship of Polyoxometallate-Confined Single Atom Electrocatalyst and Polyoxometallate-Modified Multifunctional Separator for Neutral Zn-Air Batteries.
Small
August 2025
EEC Division, CSIR-Central Electrochemical Research Institute, Karaikudi, Tamilnadu, 630003, India.
The practical application of neutral Zn-air batteries (ZABs) is severely hindered by sluggish kinetics of oxygen reduction/evolution reaction (ORR/OER) and dendrite growth on the Zn anode. A precisely controlled preparation of Fe single atoms (FSAs) is achieved on a Fe-substituted HPWO∙nHO (abbr. {FePWO}) dotted Co/N doped carbon (Co-N-C), which ensures a well-dispersed, stable, and high loading (3.
View Article and Find Full Text PDFFabrication of High-Loading Single Atom Catalysts for Energy-related Catalysis.
Small
August 2025
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, China.
Heterogeneous single-atom catalysts (SACs) have emerged as a new frontier in the field of energy-related catalysis owing to the maximum atomic utilization efficiency, unique electronic and geometric properties compared with traditional nano-catalysts. Nevertheless, it is still a great challenge to fabricate high-loading SACs, since these isolated metal sites with high surface free energy are apt to assemble into clusters or particles with a high metal content. This review summarizes recent advancements for high-loading SACs, and mainly focuses on the synthetic strategies, unique interatomic interactions, together with their applications in different chemical reactions, including photocatalysis, electrocatalysis, and thermocatalysis.
View Article and Find Full Text PDFUniversal Metal-Exchange Strategy for Room Temperature Synthesis of Single-Atom Nanozymes.
Angew Chem Int Ed Engl
July 2025
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Organic-Inorganic Composites, Beijing Laboratory of Biomedical Materials, Bionanomaterials & Translational Engineering Laboratory, Beijing Key Laboratory of Bioprocess, Beijing University of Chemical
The high-temperature limitations of single-atom catalysts (SACs) synthesis, primarily thermal aggregation and low metal loadings, are overcome by a novel room-temperature metal-exchange strategy. We leverage the weak Zn─N coordination in high-loading Zn SACs (12.10 wt%, synthesized via controlled ZIF-8 pyrolysis) as a platform for the facile exchange with a broad range of metals (Mn, Fe, Co, Ni, Cu, Ru, Pt, up to 12.
View Article and Find Full Text PDF