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Article Abstract
CsPbI, as a rarely investigated member of the CsPbX (X is a halogen element) family, has been successfully synthesized at low temperatures, and the synthetic conditions have been optimized. Metal iodides such as LiI, KI, NiI, CoI, and ZnI, as additives, play an important role in enhancing the formation of the CsPbI microcrystals. ZnI with the lowest dissociation energy is the most efficient additive to supply iodide ions, and its amount of addition has also been optimized. Strong red to near-infrared (NIR) emission properties have been detected, and its optical emission centers have been identified to be numerous embedded perovskite-type α-CsPbI nanocrystallites (∼5 nm in diameter) based on investigations of temperature- and pressure-dependent photoluminescent properties. High-resolution transmission electron microscopy was used to detect these hidden nanoparticles, although the material was highly beam-sensitive and confirmed a "raisin bread"-like structure of the CsPbI crystals. A NIR mini-LED for the biological application has been successfully fabricated using as-synthesized CsPbI crystals. This work provides information for the future development of infrared fluorescent nanoscale perovskite materials.
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