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Chitosan is a promising substitute for heavy metal ion adsorbents. However, traditional pure chitosan adsorbents have certain disadvantages that limit their application. In this paper, a 'top modification' strategy was used to enhance the capturing ability of chitosan adsorbents. A chitosan aerogel was prepared via physical crosslinking and then enhanced by immersion in ethylenediamine tetraacetic anhydride solution. Finally, an enhanced chitosan aerogel was obtained, and analyses were used to describe its structure, adsorption properties and mechanism. Results showed that both the porous structure and the combined complexations dramatically improved the capturing ability of the chitosan aerogel for heavy metal ions. The theoretical adsorption capacities of the enhanced aerogel for Cu, Pb and Cd reached 108.14, 143.73 and 84.62 mg/g, respectively. Due to their environmental friendliness, good adsorption performance, easy separation and reusability, enhanced aerogels have become viable solutions to removing heavy metal pollutants from aquatic systems.
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http://dx.doi.org/10.1016/j.jcis.2021.03.029 | DOI Listing |
Int J Biol Macromol
September 2025
Key Laboratory of Oil & Gas Fine Chemicals, School of Chemical Engineering, Xinjiang University, Urumqi, 830046, China.
With the acceleration of global industrialization, a large amount of polluted wastewater is discharged indiscriminately, which both pollutes the environment and threatens human health. In this study, by constructing a binary system of unsaturated polyester resin/carboxychitosan, and improving the inherent defects of carboxychitosan aerogel, we successfully prepared aerogels with high porosity, low density, and laminar porous structure for water remediation by using a combination of the sol-gel method and directional freezing technology. Thanks to the synergistic effect of surface wettability and special pore structure, the aerogel not only adsorbs and separates MB and Pb(II) efficiently with a separation efficiency of more than 99 %, but also has a separation efficiency of 99.
View Article and Find Full Text PDFPressure ulcer (PU) cause metabolic disorders and ischemia via prolonged pressure, leading to secondary infection, inflammation, and vascular neuropathy. However, existing therapies rely on microenvironment, HO, low repair efficiency, and lack efficient collaborative therapy. Herein, a confined multifunctional TiO/Pt nanozyme is developed via atomic layer deposition for PUs repair.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Jiangsu Co-Innovation Centre of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, PR China. Electronic address:
In response to the urgent need for highly efficient adsorbents for natural flavonoid compounds, this study proposes a novel layered porous aerogel (TOCNS@CS) based on a synergistic hydrogen bonding/electrostatic interaction mechanism. Through a green aqueous sol-gel method, TEMPO-oxidized cellulose nanocrystals (TOCNS) were cross-linked with chitosan (CS), and combined with freeze-drying technology to construct a lightweight, recyclable adsorbent material. Density functional theory (DFT) calculations revealed the synergistic adsorption pathways of carboxyl (-COOH) and amino (-NH₂) groups, enabling ultra-high selectivity in the capture of flavonoid compounds.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215000, PR China; Wuhu Innovation New Materials Co., Ltd, Wuhu 241000, PR China. Electronic address:
As modern industry continues to advance, noise pollution is becoming increasingly severe, posing a significant threat to the global economy and human health. Given their porous structure and lightweight properties, aerogels exhibit substantial potential in the field of acoustics. Concurrently, the use of environmentally-friendly, biodegradable materials such as chitosan (CS) and polyvinyl alcohol (PVA) not only helps address environmental challenges but also contributes to reducing pollution.
View Article and Find Full Text PDFJ Adv Res
August 2025
College of Food Science and Technology, Nanjing Agricultural University, Nanjing 210095, China. Electronic address:
Introduction: Berries and vegetables are susceptible to spoilage and deterioration by impact and collision after harvest, and the key to reducing their loss is to develop buffer packaging that integrates impact resistance and preservation.
Objectives: This study aims to prepare chitosan based buffer packaging to resist potential mechanical damage and microbial infection to berries.
Methods: Chitosan-based multifunctional protective aerogel buffer package was prepared using montmorillonite, clove essential oil, and nanocellulose immobilized copper nanoparticles antibacterial fiber (CMC-Cu).