Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
A novel strategy has been proposed to produce in situ LiS at the interfacial layer between lithium anode and the solid electrolyte, by using an amorphous-sulfide-LiTFSI-poly(vinylidene difluoride) (PVDF) composite solid electrolyte (SLCSE). Besides retarding the decomposition of PVDF in CSE, the LiS-modified interfacial layer (SMIL) also improves the wettability between lithium metal and SLCSE which in turn optimizes the lithium deposition process. Our density functional theory calculation results reveal that the migration energy barrier of Li passing through SMIL is much lower than that of Li passing through LiF-modified interfacial layer (FMIL) formed from the decomposition of PVDF. The as-prepared SLCSE shows a Li ionic transference number of 0.44 and Li ion conductivity of 3.42 × 10 S/cm at room temperature, and the Li||SLCSE||LiFePO cell exhibits an outstanding rate performance with a capacity of 153, 144, 131, and 101 mAh/g at a current density of 0.05, 0.10, 0.25, and 0.50 mA/cm, respectively.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.nanolett.0c03395 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Alkali chalcogenides-assisted vapor-liquid-solid growth of WX (X = S, Se, Te).
Discov Nano
September 2025
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan.
Promoter-assisted chemical vapor deposition (CVD) has emerged as a robust strategy for the low-temperature synthesis of diverse transition metal dichalcogenides (TMDs). In these processes, promoter-induced intermediates facilitate specific reaction pathways, enabling controlled growth via vapor-solid-solid (VSS) or vapor-liquid-solid (VLS) modes. While previous studies have primarily focused on transition metal precursors, growth pathways involving engineered chalcogen-based intermediates remain underexplored due to their volatility and low melting points.
View Article and Find Full Text PDFPhase Crosslinking Strategy to Construct Impact-Resistant and Buffer-Enhanced Bilayer Hydrogels with High Interfacial Adhesion.
Small
September 2025
College of Science, Nanjing Forestry University, Nanjing, 210037, China.
Inspired by the rigid exoskeleton and elastic inner tissues of crustaceans, a bilayer gel integrating high-strength rigidity and soft cushioning with high interfacial adhesion (1060 ± 40 J m ) is developed via a stepwise solid-liquid phase crosslinking strategy. Herein, a prefrozen high-concentration polyvinyl alcohol (PVA) solution forms a solid-state structural framework, while a subsequently cast low-concentration PVA solution generates a flexible layer. Partial thawing of the frozen gel during casting triggers molecular chain interpenetration at the interface, synergistically enhanced by controlled molecular penetration, freeze-thaw cycles, and salt-induced crystallization.
View Article and Find Full Text PDFHydroxy Diphosphonic Acid-Anchored Self-Assembled Monolayers Enable Annealing-Free High-Efficiency Hole Transport Layers for Organic Solar Cells.
Small
September 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, China.
This study presents a novel carbazole derivative functionalized with hydroxy diphosphonic acid groups (HDPACz) as an efficient annealing-free hole transport layer (HTL) through strong bidentate anchoring to indium tin oxide (ITO). Compared to conventional mono-phosphonic acid counterparts, HDPACz demonstrates superior ITO surface coverage and interfacial dipole, effectively modulating the work function of ITO. Theoretical calculations reveal enhanced adsorption energy (-3.
View Article and Find Full Text PDFThermal Cross-linked Electron Transport Polymers for Suppressing Efficiency Roll-off in Green Solution-Processed Inverted OLEDs.
ACS Appl Mater Interfaces
September 2025
Organic Electronic Materials Laboratory, Department of Information Display, College of Sciences, Kyung Hee University, Seoul 02447, Republic of Korea.
Solution-processed phosphorescent inverted organic light-emitting diodes (s-IOLEDs) have garnered significant attention due to their excellent stability and high performance. However, frequently used inorganic electron transport layers usually cause exciton dissociation at the emitting layer interface, leading to low device efficiency and severe efficiency roll-off. In this work, we designed a cross-linkable triazine-grafted electron transport copolymer (PPDPT--PBCB) with a high triplet energy (3.
View Article and Find Full Text PDFCompeting Grain Growth Pathways in Anisotropic BiTe-Based Thermoelectric Nanoplates.
Adv Mater
September 2025
NRC (Nanostructure Research Centre), Wuhan University of Technology, Wuhan, 430070, China.
Thermoelectric nanoplates derived from anisotropic van der Waals (vdW) materials such as BiTe are pivotal for flexible electronics and microscale thermal management. Their performance critically depends on grain boundary (GB) microstructure, but the atomic-scale mechanisms governing grain growth in these highly anisotropic systems remain elusive. This particularly concerns the competition between individual nanoplate reshaping driven by facet stabilization and collective merging at GBs.
View Article and Find Full Text PDF