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With the increasing popularity and burgeoning progress of space technology, the development of ultralow-temperature flexible functional materials is a great challenge. Herein, we report a highly emissive organic crystal combining ultralow-temperature elasticity and self-waveguide properties (when a crystal is excited, it emits light from itself, which travels through the crystal to the other end) based on a simple single-benzene emitter. This crystal displayed excellent elastic bending ability in liquid nitrogen (LN). Preliminary experiments on optical waveguiding in the bent crystal demonstrated that the light generated by the crystal itself could be confined and propagated within the crystal body between 170 and -196 °C. These results not only suggest a guideline for designing functional organic crystals with ultralow-temperature elasticity but also expand the application region of flexible materials to extreme environments, such as space technology.
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http://dx.doi.org/10.1002/anie.202011857 | DOI Listing |
ACS Sens
March 2025
State Key Laboratory of New Textile Materials and Advanced Processing, College of Textile Science and Engineering, Wuhan Textile University, Wuhan 430200, China.
Hydrogels with a combination of mechanical flexibility and good electrical conductivity hold significant potential for various applications. Nonetheless, it is inevitable that water-based conductive hydrogels lose their elasticity and conductivity at extremely low temperatures, severely limiting their utilization in ultralow temperature environments, such as those for Arctic/Antarctic exploration. In this study, we developed a conductive hydrogel based on a double network cross-linking strategy that incorporated silk fibroin (SF) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) within a lithium bromide (LiBr) solution, which shows exceptional antifreezing (-108 °C freezing point) and excellent conductivity (16.
View Article and Find Full Text PDFAdv Mater
April 2025
School of Materials Science and Engineering University of Science and Technology Beijing, Beijing, 100083, P. R. China.
The high-capacity silicon (Si) anode usually suffers from rapid capacity decay and low Coulombic efficiency in carbonate electrolytes resulting from large volume expansion and unstable solid electrolyte interphase (SEI). In addition, the sluggish electrode kinetics in routine electrolytes at subzero temperatures severely hampers the operational capabilities of Si-based batteries. Herein, a rational electrolyte design strategy is reported to tune the solvation chemistry and interfacial behavior of the electrolyte for high-performance Si anode.
View Article and Find Full Text PDFJ Am Chem Soc
April 2024
Department of Biochemical Engineering, School of Chemical Engineering and Technology, Frontier Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering (MOE), Tianjin University, Tianjin 300350, China.
Ultralow temperature-tolerant electronic skins (e-skins) can endow polar robots with tactile feedback for exploring in extremely cold polar environments. However, it remains a challenge to develop e-skins that enable sensitive touch sensation and self-healing at ultralow temperatures. Herein, we describe the development of a sensitive robotic hand e-skin that can stretch, self-heal, and sense at temperatures as low as -78 °C.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2024
Key Laboratory of Marine Advanced Materials and Applied Technology, Ningbo Institute of Materials and Technology, Chinese Academy of Sciences, Ningbo 315201, China.
Materials with low ice adhesion and long-lasting anti-icing properties remain an ongoing challenge in ultralow temperature environments (≤-30 °C). This study presents a gel material consisting of a polymer matrix (copolymer of polyurethane and acrylamide) and an anti-icing agent, ethylene glycol (EG), designed for anti-icing applications at ultralow temperatures. The surface shows a prolonged droplet freezing delay of ca.
View Article and Find Full Text PDFMacromol Rapid Commun
November 2023
Shenzhen International Innovation Institutes of Advanced Electronic Materials, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China.
The utilization of accelerators has been a common approach to prepare low-temperature curable polyimide (PI). However, the accelerators have gradually fallen out of favor because of their excessive dosages and negative effect on the properties of PI. In this work, a new strategy of introducing accelerators by grafting to eliminate these disadvantages is presented.
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