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This study examines the influence of raw material characteristics, methods of shaping and of parameters of firing process of clay bricks, on pore-size distribution and on resistance to freeze-thaw cycles (with particular emphasis on the retention time of the specimens at the maximum achieved temperature). Pore-size distribution was measured by mercury-intrusion porosimetry, while the resistance to freeze-thaw cycles was assessed by exposing the bricks to freeze-thaw cycles (HRN B.D8.011 standard) monitoring the appearance of surface changes, decrease of compressive strength as well as the Maage factor. A correlation was set up between the Maage factor and the ratio of the compressive strength before and after freezing as a quantitative indicator of bricks resistance to frost. By using this correlation for all the examined bricks, regardless of their raw material and shaping procedure, a low coefficient of correlation (R = 0.26) was obtained. When processed separately, machine-made bricks had a significantly higher correlation coefficient value (R = 0.60) than the hand-made bricks (R = 0.28).
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http://dx.doi.org/10.3390/ma13102364 | DOI Listing |
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September 2025
College of Science, Nanjing Forestry University, Nanjing, 210037, China.
Inspired by the rigid exoskeleton and elastic inner tissues of crustaceans, a bilayer gel integrating high-strength rigidity and soft cushioning with high interfacial adhesion (1060 ± 40 J m ) is developed via a stepwise solid-liquid phase crosslinking strategy. Herein, a prefrozen high-concentration polyvinyl alcohol (PVA) solution forms a solid-state structural framework, while a subsequently cast low-concentration PVA solution generates a flexible layer. Partial thawing of the frozen gel during casting triggers molecular chain interpenetration at the interface, synergistically enhanced by controlled molecular penetration, freeze-thaw cycles, and salt-induced crystallization.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
College of Pharmacy, Guangxi University of Chinese Medicine, Nanning 530200, China. Electronic address:
Conductive hydrogels have emerged as promising materials for flexible wearable electronics; however, their facile fabrication remains challenging. This study presents an antifreeze, antibacterial, and conductive hydrogel constructed from biomacromolecules sodium carboxymethylcellulose (CMC-Na) and polyvinyl alcohol (PVA). The hydrogel was synthesized via a simple one-pot method in an ethylene glycol/water (EG/H₂O) binary solvent system, incorporating lithium chloride (LiCl) and clove essential oil (CEO), followed by a single freeze-thaw cycle.
View Article and Find Full Text PDFFood Chem
September 2025
The Engineering Technological Center of Mushroom Industry, School of Biological Science and Biotechnology, Minnan Normal University, Zhangzhou 363000, PR China; Food Science Research Institute of Zhangzhou, Minnan Normal University, Zhangzhou 363000, China. Electronic address:
An ultra-low temperature (-5 °C) enzymatic method was employed to prepare glycine-amidated pectin (Gly-Pe) and evaluate its physicochemical properties and freeze-thaw protection mechanism in surimi. After glycine grafting (12.77 %), amide bonds disrupted pectin's crystalline structure and enhanced molecular chain flexibility.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2025
Civil and Environmental Engineering Department, King Fahd University of Petroleum & Minerals, 31261, Dhahran, Saudi Arabia.
Concrete production significantly contributes to CO emissions and depletion of natural resources, leading to substantial environmental concerns. The integration of polymers into concrete has emerged as a promising innovative solution aimed at overcoming inherent limitations of traditional concrete, including brittleness, susceptibility to tracking, environmental degradation, and substantial ecological impacts. This systematic review thoroughly investigates the properties, sustainability implications, and practical challenges associated with polymer-based concrete (PBC), particularly focusing on polymer concrete composites (PCC) and polymer-modified concrete (PMC) detailing their composition, mechanical behavior, and durability.
View Article and Find Full Text PDFBioorg Med Chem Lett
September 2025
Department of Chemistry, Taras Shevchenko National University of Kyiv, Kyiv 01601, Ukraine. Electronic address:
Phospholipid-derived nanocarriers represent a versatile and chemically customizable class of drug delivery systems that self-assemble into bilayered vesicles due to their intrinsic amphiphilicity. These systems can encapsulate both hydrophilic and hydrophobic drugs through non-covalent interactions and manipulation of lipid phase behavior. This review examines the molecular and supramolecular principles underlying the formation, stability, and functional performance of key phospholipid-based nanocarriers-including liposomes, transferosomes, ethosomes, invasomes, phytosomes, pharmacosomes, and virosomes.
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