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Bio-inspired functionally graded cellular materials (FGCM) have improved performance in energy absorption compared with a uniform cellular material (UCM). In this work, sheet-based and strut-based gyroid cellular structures with graded densities are designed and manufactured by stereo-lithography (SLA). For comparison, uniform structures are also designed and manufactured, and the graded structures are generated with different gradients. The mechanical behaviors of these structures under compressive loads are investigated. Furthermore, the anisotropy and effective elastic modulus of sheet-based and strut-based unit gyroid cellular structures are estimated by a numerical homogenization method. On the one hand, it is found from the numerical results that the sheet-based gyroid tends to be isotropic, and the elastic modulus of sheet-based gyroid is larger than the strut-based gyroid at the same volume fraction. On the other hand, the graded cellular structure has novel deformation and mechanical behavior. The uniform structure exhibits overall deformation and collapse behavior, whereas the graded cellular structure shows layer-by-layer deformation and collapse behavior. Furthermore, the uniform sheet-based gyroid is not only stiffer but also better in energy absorption capacity than the uniform strut-based gyroid structure. Moreover, the graded cellular structures have better energy absorption capacity than the uniform structures. These significant findings indicate that sheet-based gyroid cellular structure with graded densities have potential applications in various industrial applications, such as in crashworthiness.
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http://dx.doi.org/10.3390/ma12132183 | DOI Listing |
Adv Mater
September 2025
Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario, N6A 5B9, Canada.
Anode-free sulfide-based all-solid-state lithium metal batteries (ASSLMBs), which eliminate the need for a lithium metal anode during fabrication, offer superior energy density, enhanced safety, and simplified manufacturing. Their performance is largely influenced by the interfacial properties of the current collectors. Although previous studies have investigated the degradation of sulfide electrolytes on commonly used copper (Cu) and stainless steel (SS) current collectors, the impact of spontaneously formed surface oxides, such as copper oxide (CuO/CuO) and chromium oxide (CrO), on interfacial stability remains underexplored.
View Article and Find Full Text PDFInt J Phytoremediation
September 2025
Department of Environmental Engineering, Faculty of Engineering and Architecture, Nevsehir Haci Bektas Veli University, Nevsehir, Turkey.
The green synthesis method is a significant approach that offers several advantages, including simplicity, rapidity, and cost-effectiveness in the synthesis of nanoparticles. Iron nanoparticles were synthesized in this work using waste banana peel extract as a capping and reducing agent. The produced nanoparticles were then subjected to a number of characterization procedures, such as Raman spectroscopy, X-ray diffractometry (XRD), zeta potential analysis, Fourier transform infrared (FT-IR) spectroscopy, ultraviolet-visible (UV-VIS) absorption spectroscopy, field scanning electron microscopy (FE-SEM), energy dispersive X-ray analysis (EDX), and thermogravimetric analysis (TGA).
View Article and Find Full Text PDFBiophys J
September 2025
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee.
The concept of the circular bioeconomy is a carbon neutral, sustainable system with zero waste. One vision for such an economy is based upon lignocellulosic biomass. This lignocellulosic circular bioeconomy requires CO absorption from biomass growth and the efficient deconstruction of recalcitrant biomass into solubilized and fractionated biopolymers which are then used as precursors for the sustainable production of high-quality liquid fuels, chemical bioproducts and bio-based materials.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin, 150040, China. Electronic address:
With the exhaustion of fossil fuels, prior phase change materials are characterized by such drawbacks as poor thermal conductivity, weak shape stability, and high costs. Therefore, the preparation of phase change materials with brilliant thermal-insulating properties, high thermal conductivity, and leakage-free properties has emerged as a crucial research focus. Herein, a sericultural mulberry branch-derived (SMB) composite phase change material was prepared by deep eutectic solvent pretreated SMB and vacuum-assisted impregnated paraffin wax with cupric oxide (CuO).
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
School of Light Industry and Engineering, South China University of Technology, Guangzhou 510640, China. Electronic address:
The emergence of special scenarios involving small-sized penetrating wounds has imposed stricter performance requirements on shape-recovery hemostatic materials, particularly regarding their shape fixity and water-triggered shape recovery efficiency. Herein, an efficient shape-recovery sponge dressing with high shape fixity and high-speed liquid absorption, designated as CQT, was developed by integrating a sieve structure with the rough surface coating. The sieve structure, characterized by microporous structures on macroporous walls, enhanced the multi-level and connectivity of the overall pore network, which could improve compressive fixity via enhancing the energy dissipation required for rebound and enabled efficient shape recovery through augmented capillary action during fluid absorption.
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