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Dyes are used in various industries as coloring agents. The discharge of dyes, specifically synthetic dyes, in wastewater represents a serious environmental problem and causes public health concerns. The implementation of regulations for wastewater discharge has forced research towards either the development of new processes or the improvement of available techniques to attain efficient degradation of dyes. Catalytic oxidation is one of the advanced oxidation processes (AOPs), based on the active radicals produced during the reaction in the presence of a catalyst. This paper reviews the problems of dyes and hydroxyl radical-based oxidation processes, including Fenton's process, non-iron metal catalysts, and the application of thin metal catalyst-coated tubular reactors in detail. In addition, the sulfate radical-based catalytic oxidation technique has also been described. This study also includes the effects of various operating parameters such as pH, temperature, the concentration of the oxidant, the initial concentration of dyes, and reaction time on the catalytic decomposition of dyes. Moreover, this paper analyzes the recent studies on catalytic oxidation processes. From the present study, it can be concluded that catalytic oxidation processes are very active and environmentally friendly methods for dye removal.
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http://dx.doi.org/10.3390/ijerph16112066 | DOI Listing |
Langmuir
September 2025
Key Laboratory of Functional Molecular Solids (Ministry of Education), College of Chemistry and Materials Science, Anhui Key Laboratory of Biomedical Materials and Chemical Measurement, Anhui Normal University, Wuhu 241000, China.
The sluggish kinetics and diffusion of lithium polysulfide (LiPS) intermediates lead to the decline in the capacity and rate of high-energy lithium-sulfur (Li-S) batteries. Integrating adsorbents and electrocatalysts into the Li-S system is an effective strategy for suppressing the polysulfide shuttle and enhancing the redox kinetics of sulfur species. The disordered structure of the electrocatalysts exhibits significantly enhanced catalytic activity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, 333 Long Teng Road, Shanghai 201620, P.R. China.
Silicon carbide (SiC) membranes combine exceptional chemical, thermal, and mechanical stability but suffer from surface inertness that precludes functionalization. Conversely, MOFs offer unmatched molecular selectivity but are typically powders, severely limiting their practical use. To address this, we develop a generalizable route to fabricate ultrastable MOF@SiC membranes via sequential oxidation and acidification, creating abundant Si-OH sites on SiC surfaces that covalently bond with Zr-MOF crystals; the bonding mechanism between MOFs and substrates has been extensively studied.
View Article and Find Full Text PDFAdv Mater
September 2025
Department of Minimally Invasive Interventional Radiology, The Second Affiliated Hospital &Guangzhou Institute of Cancer Research, The Affiliate Cancer Hospital &School of Biomedical Engineering, Guangzhou Medical University, Guangzhou, 510260, China.
Surgical resection remains the frontline intervention for cancer; however, postoperative tumor recurrence and wound infection remain critical unmet challenge in surgical oncology. Herein, an all-in-one nanowired hydrogel (V-Hydrogel) is developed through a facile one-step assembly employing enzyme-mimetic VO nanowires and bactericidal crosslinker THPS. The V-Hydrogel reserves the glutathione peroxidase-, peroxidase-, catalase-, and oxidase-mimetic enzymatic activities derived from vanadium oxide nanowires, thereby exhibiting efficient tumor-specific catalytic therapy.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand.
The accumulation of nitrate (NO) from agricultural runoff poses a growing threat to ecosystems and public health. Converting nitrate into ammonia (NH) through the electrochemical nitrate reduction reaction (NORR) offers a promising strategy to mitigate environmental contamination while creating a sustainable circular route to fertilizer production. However, achieving high NH production and energy efficiency remains challenging.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Confucius Energy Storage Lab, School of Energy and Environment & Z Energy Storage Center, Southeast University, Nanjing 211189, China.
Developing efficient and durable catalysts for the oxygen evolution reaction (OER) in acidic media is essential for advancing proton exchange membrane water electrolysis (PEMWE). However, catalyst instability caused by lattice oxygen (O) depletion and metal dissolution remains a critical barrier. Here, we propose an oxophilic-site-mediated dynamic oxygen replenishment mechanism (DORM), in which O actively participates in O-O bond formation and is continuously refilled by water-derived species.
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