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Article Abstract
Excellent fluorescence properties are exhibited by d metal compounds. The novel three-dimensional Zn coordination framework, poly[[{μ-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κN:N}(μ-furan-2,5-dicarboxylato-κO:O)zinc(II)] 1.76-hydrate], {[Zn(CHO)(CHNO)]·1.76HO}, has been prepared and characterized using IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure analysis revealed that the compound exhibits a novel fourfold interpenetrating diamond-like network. This polymer also displays a strong fluorescence emission in the solid state at room temperature.
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| http://dx.doi.org/10.1107/S2053229619004303 | DOI Listing |
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