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Article Abstract
-Oligo(phenylene)ethynylenes (-OPEs) stapled with enantiopure 2,3-dihydroxybutane diethers have highly intense circular dichroism (CD) spectra and excellent circular polarized luminescence (CPL) responses ( values up to 1.1 × 10), which are consistent with homochiral helically folded structures. In the presence of Ag(i), a change in the CPL emission is observed, representing the first example of CPL active small organic molecular emitters, which can be modulated by carbophilic interactions in a reversible manner.
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| http://dx.doi.org/10.1039/c6sc01808d | DOI Listing |
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