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Article Abstract
The radical bridged compound [(Ni(TPMA))-μ-bmtz](BF)·3CHCN (bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine, TPMA = tris(2-pyridylmethyl)amine) exhibits strong ferromagnetic exchange between the S = 1 Ni centers and the bridging S = 1/2 bmtz radical with J = 96 ± 5 cm (-2JSS). DFT calculations support the existence of strong ferromagnetic exchange.
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