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Inspired by Steller's jay, which displays angle-independent structural colors, angle-independent structurally colored materials are created, which are composed of amorphous arrays of submicrometer-sized fine spherical silica colloidal particles. When the colloidal amorphous arrays are thick, they do not appear colorful but almost white. However, the saturation of the structural color can be increased by (i) appropriately controlling the thickness of the array and (ii) placing the black background substrate. This is similar in the case of the blue feather of Steller's jay. Based on the knowledge gained through the biomimicry of structural colored materials, colloidal amorphous arrays on the surface of a black particle as the core particle are also prepared as colorful photonic pigments. Moreover, a structural color on-off system is successfully built by controlling the background brightness of the colloidal amorphous arrays.
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http://dx.doi.org/10.1002/adma.201605050 | DOI Listing |
Adv Mater
September 2025
College of Integrated Circuits & Micro-Nano Electronics, Fudan University, Shanghai, 200433, China.
High-operating-temperature (HOT) mid-wavelength and long-wavelength infrared photodetectors have emerged as critical enablers for eliminating bulky cryogenic cooling systems, offering transfromative potential in developing compact, energy-efficient infrared technologies with reduced size, weight, power, and cost. Focusing on infrared photodiodes, this review first discusses the fundamental mechanisms limiting performance at elevated operating temperatures. Subsequently, the progress in conventional epitaxial semiconductors, such as HgCdTe, InAsSb, and III-V type-II superlattice is reviewed, highlighting the evolution of device architectures designed to effectively suppress dark currents and approach background-limited performance.
View Article and Find Full Text PDFMikrochim Acta
September 2025
Affordable and Sustainable Sample Preparation (AS2P) Research Group, Departamento de Química Analítica, Instituto Químico para la Energía y el Medioambiente IQUEMA, Universidad de Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, E-14071, Córdoba, Spain.
Stainless-steel substrates have grown in importance in the development of planar sorptive phases. However, the reduced wettability of polished sheets makes difficult their functionalization. This limitation can be solved by using amorphous silica gel microparticles as superficial guides.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Hebei Provincial Key Laboratory of Green Chemical Technology and High Efficient Energy Saving, Tianjin Key Laboratory of Chemical Process Safety, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China. Electronic address:
Enhancing anodic hydroxyl (OH) coverage and suppressing leaching of active metal sites are essential for developing efficient and durable alkaline oxygen evolution reaction (OER) electrocatalysts. Herein, we propose amorphous cerium oxide (CeO)-mediated amorphous/crystalline heterointerface engineering to enhance OH coverage and leaching resistance in CeO/Mo-NiS for high-performance OER. CeO with an oxyphilic surface facilitates OH adsorption, promoting in situ reconstruction of NiS into nickel hydroxyl oxide (NiOOH) with significantly enhanced OH coverage and thereby accelerating OER kinetics.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
School of Marine Science and Engineering, Hainan University, Haikou 570228, China. Electronic address:
Precise regulation of self-reconstruction in metal-organic frameworks (MOFs) presents a promising strategy for designing high-performance oxygen evolution reaction (OER) electrocatalysts. In this study, we introduce an amorphization strategy to induce profound self-reconstruction in bimetallic tetrathiafulvalene tetrabenzoate (HTTFTB) MOFs supported on nickel foam (NF). The optimized CoFe-TTFTB@NF electrocatalyst exhibits remarkably low overpotentials (228 mV at 10 mA cm, 267 mV at 100 mA cm) and maintains stability for 200 h at 100 mA cm, outperforming commercial RuO and most reported MOF-based catalysts.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, Zhejiang, PR China. Electronic address:
The sluggish kinetics of the oxygen evolution reaction (OER) necessitate the use of efficient, non-precious metal catalysts. This work reports the rational design of an indium-doped bimetallic metal-organic framework (MOF-74-CoIn) as a precatalyst, achieved through post-synthetic modification of MOF-74-Co. Structural and spectroscopic analyses confirm that In(III) incorporation induces CoO bond contraction while preserves the overall structural integrity.
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