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Ceramic matrix composites (CMCs) are structural materials, which have useful properties that combine high strength at high temperatures with moderate toughness. Carbon fibers within a matrix of carbon and silicon carbide, called C/C-SiC, are a particular class of CMC noted for their high oxidation resistance. Here we use a combination of four-point bending and X-ray radiography, to study the mechanical failure of C/C-SiC CMCs. Correlating X-ray radiographic and load/displacement curve data reveals that the fiber bundles act to slow down crack propagation during four-point bending tests. We attribute this to the fact that strain energy is expended in breaking these fibers and in pulling fiber bundles out of the surrounding matrix material. In addition, we find that the local distribution and concentration of SiC plays an important role in reducing the toughness of the material.
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http://dx.doi.org/10.1017/S1431927617000459 | DOI Listing |
ACS Omega
September 2025
Department of Physics, Birla Institute of Technology and Science, Pilani, Pilani Campus, Vidya Vihar, Pilani, Rajasthan 333031, India.
We report the performance of solid-state ceramic supercapacitors (SSCs) based on a novel composite electrolyte comprising aluminum-doped lithium lanthanum titanate perovskite, LiLaTiAlO (Al-doped LLTO), and the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIM BF). Rietveld refinement of X-ray diffraction data confirms the preservation of the tetragonal perovskite phase after Al substitution, indicating structural stability of the host lattice. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy further corroborate the successful incorporation of Al without forming secondary phases.
View Article and Find Full Text PDFACS Omega
September 2025
Department of Physics, Federal University of Sergipe, 49100-000 São Cristovão, SE, Brazil.
Hybrid coatings composed of crystalline monetite (CaHPO) and kefir-derived Dextran were synthesized on Ti6Al4V substrates using a low-temperature sol-gel-assisted route (≤80 °C), enabling biopolymer integration without thermal degradation. X-ray diffraction (XRD) confirmed the formation of triclinic monetite nanocrystals (∼152 nm), while Fourier transform infrared (FTIR) and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) analyses verified the uniform incorporation of Dextran, particularly in the 4 wt % formulation, which yielded compact, homogeneous surfaces. Electrochemical evaluations in Fusayama artificial saliva revealed a substantial enhancement in corrosion resistance, with the open-circuit potential shifting from -0.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.
Partial crystallization within a glass matrix to form microcrystalline domains offers a pathway to glass-ceramic materials with properties distinct from those of both the parent glass and crystalline phases. This concept has been limited to inorganic glasses. Here, we introduce metal-organic crystallized glasses (MOCGs), prepared by controlling the crystallization process within metal-organic framework (MOF) glasses, and explore their properties.
View Article and Find Full Text PDFSmall Methods
September 2025
School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China.
Gel polymer electrolytes (GPEs) with solvent-in-polymer structure typically encounter a trade-off between ionic conductivity and mechanical properties. This challenge has not been adequately addressed by conventional single-material, miscible polymers, or polymer/ceramic composite electrolytes. Herein, the phase consistency of composite GPE matrix, which contains polymer blends of "soft" poly(vinylidene fluoride-co-hexafluoropropylene) (PVHF) and "hard" polyether-ether-ketone (PEEK), is enhanced by ion-mediated compatibilization through the incorporation of lithium sulfonate groups.
View Article and Find Full Text PDFZhonghua Kou Qiang Yi Xue Za Zhi
September 2025
Department of Prosthodontics I, Stomatological Hospital of Xiamen Medical College & Xiamen Key Laboratory of Stomatological Disease Diagnosis and Treatment, Xiamen 361008, ChinaLin Jing works at Department of Stomatology, Affiliated Hospital of Putian University, Putian 351100, China.
To investigate the effects of nine polishing protocols on the bonding interface of three types of resin-based ceramic onlays, aiming to identify efficient and reasonable polishing procedures for each type of resin-based ceramic. Forty-six extracted molars were selected and symmetrically sectioned mesiodistally (=92). After preparing 2 mm deep box-shaped cavities on the buccal and lingual surfaces, the samples were randomly divided into four groups (23): LU group (Lava Ultimate), VE group (Vita Enamic), H group (Zirconia-Reinforced Resin-Based Ceramic), and Si group (glass ceramic).
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